@article{oai:kanazawa-u.repo.nii.ac.jp:00055419, author = {Tazaki, Kazue and Hasegawa, Kaori and Matsumoto, Kazuya and 田崎, 和江 and 長谷川, 香織 and 松本, 和也}, issue = {2}, journal = {地球科学, Earth Science}, month = {Mar}, note = {かつての鉱山活動は重金属を外界に排出し,今日でも水質や土壌汚染の原因となっている.岐阜県神岡町にある大規模なZn-Pb鉱山の一つである神岡鉱山は,神通川の重金属汚染源となってきた.Cd,Pb,ZnそしてFeなどの重金属が高原川-神通川水系に未処理のまま廃棄され,下流域の住民の健康に影響を与えた.重金属の中でも特にCdは,イタイイタイ病の病原物質と見なされた.Cd汚染問題は未だに解決されていない.消石灰を投入し,中和凝集処理された廃滓の沈殿池が神岡鉱山にいくつか存在する.廃滓や廃棄場から排出された汚染水は,神通川の上流の高原川に流れ込んでいる.本研究では,重金属を含む堆積物の特性を明らかにするため,高原川-神通川水系にある五つのダムの堆積物を採取した.ダム堆積物の鉱物的・化学的組成を明らかにするため,それぞれの試料についてXRD,ED-XRFによる分析を行った.その結果,神岡鉱山の上流域に位置する浅井田ダムの堆積物はCd,粘土鉱物そして有機物が少なく,神岡鉱山の下流域に位置する新猪谷ダム,神通川第一,第二,第三ダムにおいては,汚泥,スメクタイトそしてZn,Cdのような重金属が多く含まれていることが明らかになった.また,本研究では,水中の重金属の浄化能力を見積もるための実験を行った.その結果,バクテリアを使ったバイオレメディエーションは重金属の固定に効果的であることを示した.室内実験系においてバイオフロック中の糸状菌は,一週間で細胞壁の表面にPb,Zn,Cdを選択的に濃集した.バイオレメディエーションの能力を持つバクテリアは,鉱山地域における下流のダム堆積物中でも重金属を固定する重要な役割を演じている., Contamination of water and soils is one of grave problems at mining area. Kamioka Mine, one of the largest Zn-Pb mine in Gifu prefecture in Japan, has been the source of heavy metal pollution in Jinzu River. Cd, Pb, Zn, and Fe have been released from an abandoned dump into the Takahara-Jinzu River system, and serious health problem occurred in the down stream areas. Heavy metals, Cd, in particular, is regarded to be the pathogenic substance causing Itai-Itai Disease. The Cd pollution problems have not yet been solved. Some tailing ponds with neutralizing coagulation treatment (slaked lime) are present in the Kamioka Mine. Heavy metal-contaminated wasted water from tailing and dumping areas were discharged into the Takahara River (the upper stream of the Jinzu River). In this study, five dam sediments along the Takahara-Jinzu River were collected, in order to clarify characteristics of sediments with heavy metals. Each sample was analyzed by using an X-ray powder diffractometer (XRD) and an energy dispersive X-ray fluorescence analyzer (ED-XRF) in order to clarify the mineralogical and chemical compositions of the dam sediments. As a result, the sediment from Asaida dam on the upper course of the Kamioka Mine has little Cd, clay minerals and organic matter, whereas Shininotani dam, Jinzu 1st dam, Jinzu 2nd dam, Jinzu 3rd dam in the down stream of the Kamioka Mine have much sludge, smectite and heavy metals, such as Zn and Cd. Smectite and organic matter have been concentrated with heavy metals in the down stream dam sediments of Jinzu River. In this study, arrange of experimental observation has carried out in order to estimate the ability of heavy metals for the purification of water. The results suggest that bioremediation methods using bacteria is effective as a fixing heavy metals. Filamentous bacteria in biofloc selectively accumulated Pb, Zn, and Cd on the surface of cell wall in laboratory experimental system after one week aging. The bacteria have an ability as a bioremediation, play a key role in the fixation of heavy metals in the down stream dam sediments at mining area., 金沢大学理工研究域地球社会基盤学系}, pages = {87--104}, title = {神通川流域におけるダム堆積物中の重金属の挙動と微生物による浄化法の試み}, volume = {56}, year = {2002} }