{"created":"2023-07-27T06:59:38.963499+00:00","id":59301,"links":{},"metadata":{"_buckets":{"deposit":"bc2310ae-a89e-45c8-9946-8cf98a7c4408"},"_deposit":{"created_by":18,"id":"59301","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"59301"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00059301","sets":["4161:3020:3021"]},"author_link":["80165","79771","104684","104685","104686","104689","104690","80110","81651","79770","366","2558","1779","80166","104687","85219"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-04-09","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"14","bibliographicPageEnd":"7767","bibliographicPageStart":"7760","bibliographicVolumeNumber":"124","bibliographic_titles":[{"bibliographic_title":"Journal of Physical Chemistry C"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"淺川, 雅"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"生越, 友樹"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"太田, 明雄"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"淺川, 毅"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"福間, 剛士"}],"nameIdentifiers":[{},{},{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The self-assembly of organic molecules at the surface of highly oriented pyrolytic graphite (HOPG) is a promising process for constructing molecular-scale architectures. However, selectable organic molecules are generally restricted to two-dimensional molecules with planar Ï-conjugated structures and alkyl chains. We herein present the formation of self-assembled monolayers of tetrakis(4-ethynylphenyl)methane (TEPM) having a three-dimensional (3D) tetrapod geometry on HOPG, which was achieved by utilizing a simple spin-coating method. The arrangements of TEPM molecules in the monolayers were investigated using frequency-modulation atomic force microscopy (FM-AFM). The resulting subnanometer-resolution FM-AFM images revealed that the TEPM molecules formed linear rows with a periodicity of 0.85 nm oriented in a parallel configuration but with two alternating intervals of 0.7 and 1.0 nm. Moreover, the TEPM monolayers were classified into two chiral types with a relationship of mutual mirror-image symmetry, according to the observed molecular arrangements. Our results demonstrate the capability of TEPM molecules to act as 3D building blocks for the design of molecular-scale architectures at interfaces. Copyright © 2020 American Chemical Society.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学ナノ生命科学研究所 / 金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00065563","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.jpcc.9b11246","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://pubs.acs.org/journal/jpccck/about.html"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://pubs.acs.org/journal/jpccck/about.html","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"http://pubs.acs.org/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://pubs.acs.org/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://pubs.acs.org/doi/10.1021/acs.jpcc.9b11246"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acs.jpcc.9b11246","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2020 American Chemical Society"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA1217589X","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1932-7447","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1932-7455","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Asakawa, Hitoshi"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Matsui, Sayaka"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Trinh, Quang Than"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hirao, Hajime"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Inokuma, Yasuhide"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ogoshi, Tomoki"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Tanaka, Saki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Komatsu, Kayo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohta, Akio"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Asakawa, Tsuyoshi"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Fukuma, Takeshi"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-03-11"}],"displaytype":"detail","filename":"SC-PR-ASAKAWA-T-124-7760.pdf","filesize":[{"value":"7.3 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-ASAKAWA-T-124-7760.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/59301/files/SC-PR-ASAKAWA-T-124-7760.pdf"},"version_id":"fba38e6b-c34f-44eb-9eb4-c82b36af6ee5"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite"}]},"item_type_id":"4","owner":"18","path":["3021"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-03-11"},"publish_date":"2022-03-11","publish_status":"0","recid":"59301","relation_version_is_last":true,"title":["Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T10:12:51.389746+00:00"}