{"created":"2023-07-27T07:00:11.205136+00:00","id":60023,"links":{},"metadata":{"_buckets":{"deposit":"1c5e4d58-f79b-469a-99df-70043683a148"},"_deposit":{"created_by":18,"id":"60023","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"60023"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00060023","sets":["2812:2813:2838"]},"author_link":["27765","27759"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04-21","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"2p.","bibliographicVolumeNumber":"1995","bibliographic_titles":[{"bibliographic_title":"平成7(1995)年度 科学研究費補助金 一般研究(C) 研究概要"},{"bibliographic_title":"1995 Research Project Summary","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1.スチリルシラン体を芳香族ヨード化合物とのパラジウム触媒によるカップリング反応で効率のよいオルトスチリル安息香酸誘導体の合成法を開拓した。\n2.先に我々の開発したベンゾキノン存在下のPdCl2(GH3CN)2を用いる触媒的アシロキシパラデーション法により、前記オルトスチリル安息香酸からフェニルイソクマリン誘導体への閉環に成功した。\n3.前項の反応条件を変えることにより、抗腫瘍性のベンゾフェナンスリジン骨格の酸素等配体であるベンゾ[d]ナフト[1,2-b]ピラン体の一工程変換法を開発した。\n4.フェニルイソクマリン体からラクタム体を経る抗腫瘍活性アルカロイドのニチジンの新規合成に成功した。\n5.6位にアミノエチル基が置換したピリドアクリジン骨格の合成ルートを開拓し、抗腫瘍活性海洋産アルカロイドのシストジチンJ及びジプラミンの全合成に成功した。","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:07672262, 研究期間(年度):1995","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「抗腫瘍性ベンゾフェナンスリジン化合物および酸素等配体の合成」課題番号07672262\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07672262/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学薬学部","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00066274","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=80028844"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80028844","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07672262/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07672262/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-06-06"}],"displaytype":"detail","filename":"PH-PR-HANAOKA-M-kaken 2016-2p.pdf","filesize":[{"value":"122.9 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-HANAOKA-M-kaken 2016-2p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/60023/files/PH-PR-HANAOKA-M-kaken 2016-2p.pdf"},"version_id":"193b9063-653f-4817-a1b9-fbd09a32d956"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"抗腫瘍性ベンゾフェナンスリジン化合物および酸素等配体の合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"抗腫瘍性ベンゾフェナンスリジン化合物および酸素等配体の合成"}]},"item_type_id":"9","owner":"18","path":["2838"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-06-06"},"publish_date":"2022-06-06","publish_status":"0","recid":"60023","relation_version_is_last":true,"title":["抗腫瘍性ベンゾフェナンスリジン化合物および酸素等配体の合成"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T12:55:21.209689+00:00"}