{"created":"2023-07-27T07:00:30.617529+00:00","id":60463,"links":{},"metadata":{"_buckets":{"deposit":"ecaaff25-7b9b-4cf4-8e47-0742836b920b"},"_deposit":{"created_by":18,"id":"60463","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"60463"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00060463","sets":["2812:2813:2840"]},"author_link":["27765","27759"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04-21","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"2p.","bibliographicVolumeNumber":"1993","bibliographic_titles":[{"bibliographic_title":"平成5(1993)年度 科学研究費補助金 一般研究(C) 研究課題概要"},{"bibliographic_title":"1993 Research Project Summary","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1.海洋産アルカロイドの共通骨格である4-arylquinoline骨格の一工程合成としてp-benzoquinoneと各種3-arylpropanol N,N-dimethylhydrazoneとのヘテロDiels-Alder反応を検討し、MnO_2存在下2,6-dichlorobenzoquinoneを用いることにより、この種ヘテロDiels-Alder反応に初めて成功した。\n2.上記の成績体から官能基変換を経て4環性共通骨格の5-chloro-4-oxo-4H-pyrido[2,3,4-kl]acridineの合成に成功した。本化合物からのアルカロイド合成を検討中である。\n3.上記のヘテロDiels-Alder成績体から5環性海洋産アルカロイドのamphimedine,7環性アルカロイドeillatinの合成中間体に導き、これらアルカロイドの形式合成を達成した。\n4.ヘテロキノンの新しい合成法としてクロトン酸エステルを部分構造を有するヘテロ環とphenyl β-trimethylsilylvinyl sulfoneとのanionic cycloaddition法を経る新しいcarbazolequinone合成法を開発し、これを応用したmurrayaquinone Aの全合成に成功した。","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:05671746, 研究期間(年度):1993","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「抗腫瘍性多環式海洋産アルカロイドの合成」課題番号05671746\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-05671746/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学薬学部","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00066711","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=80028844"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80028844","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-05671746/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-05671746/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-07-08"}],"displaytype":"detail","filename":"PH-PR-HANAOKA-M-kaken 2016-2p.pdf","filesize":[{"value":"118.1 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-HANAOKA-M-kaken 2016-2p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/60463/files/PH-PR-HANAOKA-M-kaken 2016-2p.pdf"},"version_id":"0a58bbe5-f01c-4fe5-ad6a-d6007d0add01"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"抗腫瘍性多環式海洋産アルカロイドの合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"抗腫瘍性多環式海洋産アルカロイドの合成"}]},"item_type_id":"9","owner":"18","path":["2840"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-07-08"},"publish_date":"2022-07-08","publish_status":"0","recid":"60463","relation_version_is_last":true,"title":["抗腫瘍性多環式海洋産アルカロイドの合成"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T12:39:47.172257+00:00"}