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Measurement and correlation for solubilities of alkali metal chlorides in water vapor at high temperature and pressure
http://hdl.handle.net/2297/6635
http://hdl.handle.net/2297/6635c184f144-d9e2-4e2f-930e-98b79a6a9446
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Measurement and correlation for solubilities of alkali metal chlorides in water vapor at high temperature and pressure | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Higashi, Hidenori
× Higashi, Hidenori× Iwai, Yoshio× Matsumoto, Kota× Kitani, Yoshiaki× Okazaki, Fumio× Shimoyama, Yusuke× Arai, Yasuhiko |
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提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学大学院自然科学研究科生産プロセス | |||||
書誌情報 |
Fluid Phase Equilibria 巻 228-229, p. 547-551, 発行日 2005-02-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0378-3812 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.fluid.2004.07.019 | |||||
出版者 | ||||||
出版者 | Elsevier | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A flow type apparatus was designed and constructed to measure the solubilities of salts in water vapor at high temperature and pressure. The apparatus was equipped with an additional pure water line to prevent the clogging by precipitated solid salts at the outlet of an equilibrium cell. The solubilities of sodium chloride and potassium chloride in water vapor were measured at 623-673 K and 9.0-12.0 MPa. In order to verify the soundness of this method and the performance of the apparatus, the experimental results for the solubilities of sodium chloride at 673 K were compared with the literature data. The present data are in good agreement with the literature data. The solubilities of sodium chloride are similar to those of potassium chloride at the same temperatures and pressures. The isobaric solubilities decrease with increasing temperature at the experimental pressure range. The experimental results of solubilities were correlated by a solution model. The molar volumes and the energy parameters of salts were treated as adjustable parameters and were optimized with the present and literature data. The adjusted energy parameters for salts can be related to a linear function of the temperature. The correlated results show good agreement with the experimental data. © 2004 Elsevier B.V. All rights reserved. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.elsevier.com/locate/issn/03783812 |