{"created":"2023-07-27T06:24:50.813951+00:00","id":7911,"links":{},"metadata":{"_buckets":{"deposit":"c3a584bf-085d-4b23-bf43-f44b6f75f65b"},"_deposit":{"created_by":3,"id":"7911","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"7911"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00007911","sets":["934:935:936"]},"author_link":["10879","3945","10880","10881","10640"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"1970","bibliographicPageStart":"1963","bibliographicVolumeNumber":"12","bibliographic_titles":[{"bibliographic_title":"Physical Chemistry Chemical Physics"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The photochemistry of the benzophenone ketyl radical in D1 excited state, BPH(D1), was studied by means of two-color dual-pulse laser flash photolysis (355 and 532 nm) in a room-temperature ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide (Bmim-TFSA), and in methanol. Upon excitation with the 532 nm pulse, BPH(D1) emitted strong fluorescence. The transient absorption and fluorescence spectra of BPH(D1) were measured with nanosecond and sub-nanosecond time resolution, respectively. The observed Stokes shift was 1700 cm-1 in Bmim-TFSA, and this shift was close to that in acetonitrile. The fluorescence lifetime of BPH(D1) was determined to be 5 ns in Bmim-TFSA, and again the value was close to that in acetonitrile. The rate constant of the reaction of BPH(D1) with CCl4 in Bmim-TFSA was determined to be (2.1 ± 0.4) × 109 M-1 s-1, which was 10 times the rate constant calculated on the basis of the bulk viscosity of Bmim-TFSA. The results are discussed in terms of the effective microscopic viscosity of the ionic liquid that was recently reported for the cage effect. © 2010 the Owner Societies.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域自然システム学系","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/b920131a","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA11301773","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1463-9076","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takahashi, Kenji"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Tezuka, Hiroaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kitamura, Shingo"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Satoh, Toshifumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Katoh, Ryuzi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"TE-PR-TAKAHASHI-K-1963.pdf","filesize":[{"value":"630.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TE-PR-TAKAHASHI-K-1963.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/7911/files/TE-PR-TAKAHASHI-K-1963.pdf"},"version_id":"6ff320f2-a869-46b7-9d65-720795ef79c0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reactions of excited-state benzophenone ketyl radical in a room-temperature ionic liquid","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reactions of excited-state benzophenone ketyl radical in a room-temperature ionic liquid"}]},"item_type_id":"4","owner":"3","path":["936"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"7911","relation_version_is_last":true,"title":["Reactions of excited-state benzophenone ketyl radical in a room-temperature ionic liquid"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T02:17:30.127940+00:00"}