{"created":"2023-07-27T06:24:56.551114+00:00","id":8038,"links":{},"metadata":{"_buckets":{"deposit":"254a56db-26d6-491a-a505-1f3e4281823c"},"_deposit":{"created_by":3,"id":"8038","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"8038"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00008038","sets":["934:935:936"]},"author_link":["604","11127","11125","11129","11126","11128"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-03-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"80","bibliographicPageStart":"73","bibliographicVolumeNumber":"42","bibliographic_titles":[{"bibliographic_title":"Spectroscopy Letters"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The crystal structures of 5-benzyl-2-thiohydantoin (5-BTH) and 1-acetyl-5-benzyl-2-thiohydantoin (1-Ac-5-BTH) have been determined by X-ray diffraction. In the 5-BTH crystals, the enantiomeric (R)- and (S)-5-BTH molecules are connected to form cyclic dimers via the hydrogen bonds of the thioamide and the amide moieties. On the other hand, the intermolecular hydrogen bonds in 1-Ac-5-BTH crystals form an infinite chain. These differences in the hydrogen bond pattern are also discussed in the IR and Raman spectra. The ab initio molecular orbital calculations (Gaussian 03) with 6-31G(d,p) basis set were carried out for 5-BTH and 1-Ac-5-BTH to get the preferred conformation. Copyright © Taylor & Francis Group, LLC.全文公開201003","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Taylor & Francis"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1080/00387010802428575","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00847833","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0038-7010","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kunimoto, Ko-Ki"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Ichitani, Masaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ogawa, Toshikazu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kitoh, Soh-ichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kuwae, Akio"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hanai, Kazuhiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"TE-PR-KUNIMOTO-K-73.pdf","filesize":[{"value":"802.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TE-PR-KUNIMOTO-K-73.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/8038/files/TE-PR-KUNIMOTO-K-73.pdf"},"version_id":"38db05af-f6d3-48ea-92a6-f9fcd3833170"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Crystal structures and conformations of 5-benzyl-2-thiohydantoin and its 1-acetylated derivative","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Crystal structures and conformations of 5-benzyl-2-thiohydantoin and its 1-acetylated derivative"}]},"item_type_id":"4","owner":"3","path":["936"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"8038","relation_version_is_last":true,"title":["Crystal structures and conformations of 5-benzyl-2-thiohydantoin and its 1-acetylated derivative"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T02:15:21.498739+00:00"}