{"created":"2023-07-27T06:19:50.124330+00:00","id":826,"links":{},"metadata":{"_buckets":{"deposit":"5d7e6b1a-6bdc-4a18-917f-557701279caa"},"_deposit":{"created_by":3,"id":"826","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"826"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00000826","sets":["11:12:16"]},"author_link":["3934","49959","7928","3932","551","3933"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1978-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"2582","bibliographicPageStart":"2578","bibliographicVolumeNumber":"51","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"井原, 良訓"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"土屋, 亮吉"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"上原, 章"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"久野, 栄進"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The following six cobalt(III) complexes containing phenylbiguanide were prepared and the thermal reactions were followed both isothermally and non-isothermally (derivatographically) in the solid phase: trans-[Co(A)2(phbgH)2]X3·n2O, where A denotes volatile ligands such as NH3, CH3NH2 or C5H5N; phbgH denotes 1-phenylbiguanide, X chloride or bromide ion; and n is 2 or 3. From the electronic, IR and far-IR spectra and magnetic susceptibilities of these complexes before and after heating, the products obtained by evolving volatile ligands were found to be uniform bivalent cobalt complexes without rupture of the bonds of phbgH to cobalt in spite of the reduction of central cobalt(III) ion, except for the complexes containing ammonia. The reaction seems to be caused by the electron transfer from the coordinated phbgH to cobalt, not from the outer-sphere anions.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会＝The Chemical Society of Japan"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.51.2578","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/journal/index.html","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/article/bcsj1926/51/9/51_9_2578/_article","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 日本化学会 The Chemical Society of Japan"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12026255","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1348-0634","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ihara, Yoshinori"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Uehara, Akira"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Tsuchiya, Ryokichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kyuno, Eishin"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-02"}],"displaytype":"detail","filename":"LE-PR-IHARA-Y-2578-2582.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"LE-PR-IHARA-Y-2578-2582.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/826/files/LE-PR-IHARA-Y-2578-2582.pdf"},"version_id":"40a03a44-1747-48be-81bf-c0a6130bc32c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Derivatographic Studies on Transition Metal Complexes. XX. Thermal Electron Transfer Reactions of Cobalt(III) Complexes Containing Phenylbiguanide in the Solid Phase","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Derivatographic Studies on Transition Metal Complexes. XX. Thermal Electron Transfer Reactions of Cobalt(III) Complexes Containing Phenylbiguanide in the Solid Phase"}]},"item_type_id":"4","owner":"3","path":["16"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-02"},"publish_date":"2017-10-02","publish_status":"0","recid":"826","relation_version_is_last":true,"title":["Derivatographic Studies on Transition Metal Complexes. XX. Thermal Electron Transfer Reactions of Cobalt(III) Complexes Containing Phenylbiguanide in the Solid Phase"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T12:15:55.998924+00:00"}