{"created":"2023-07-27T06:19:50.165523+00:00","id":827,"links":{},"metadata":{"_buckets":{"deposit":"e73a8db6-bdb3-477a-ba13-1a39f0a24d1d"},"_deposit":{"created_by":3,"id":"827","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"827"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00000827","sets":["11:12:16"]},"author_link":["7928","551","3933"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1980-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1617","bibliographicPageStart":"1614","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"土屋, 亮吉"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"井原, 良訓"}],"nameIdentifiers":[{},{},{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Thermal reactions of the complexes, [Ni(abi)4]X2·nH2O (abi, 2-aminobenzimidazole; X, Cl, Br, I, NO3, ClO4, or 1/2SO4; n, 3 for chloride and bromide, 1 for nitrate, and 0 for others) were investigated. Distinct color changes from orange to green were observed in the three complexes of chloride, bromide, and nitrate upon heating. It was found from the changes in absorption and far-IR spectra and magnetic susceptibilities under the thermal reactions that the complexes undergo transformation from square planar to tetragonally distorted octahedral structures, involving an increase in the coordination number from four to six. No such transformation could be found in the corresponding iodide, perchlorate, and sulfate. The effect of the introduced amino group on the structural conversion reactions of the abi complexes is discussed as compared with the corresponding benzimidazole complexes, [Ni(bimd)4]X2, which underwent transformation from square planar to octahedral structure upon heating when X is I or NO3.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会＝The Chemical Society of Japan"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.53.1614","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/article/bcsj1926/53/6/53_6_1614/_article","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 日本化学会 The　Chemical Society of Japan｜許可を得て登録"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12026255","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ihara, Yoshinori"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Tsuchiya, Ryokichi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-02"}],"displaytype":"detail","filename":"LE-PR-IHARA-Y-1614-1617.pdf","filesize":[{"value":"289.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"LE-PR-IHARA-Y-1614-1617.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/827/files/LE-PR-IHARA-Y-1614-1617.pdf"},"version_id":"d3d2a6b0-7c72-4786-bb66-8cd570f4a17a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Thermal Square Planar-to-Octahedral Transformation of Nickel(II) Complexes Containing 2-Aminobenzimidazole in the Solid Phase","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Thermal Square Planar-to-Octahedral Transformation of Nickel(II) Complexes Containing 2-Aminobenzimidazole in the Solid Phase"}]},"item_type_id":"4","owner":"3","path":["16"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-02"},"publish_date":"2017-10-02","publish_status":"0","recid":"827","relation_version_is_last":true,"title":["Thermal Square Planar-to-Octahedral Transformation of Nickel(II) Complexes Containing 2-Aminobenzimidazole in the Solid Phase"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T12:16:35.043905+00:00"}