{"created":"2023-07-27T06:19:50.207318+00:00","id":828,"links":{},"metadata":{"_buckets":{"deposit":"75d4103c-e32d-47df-aa23-d035b2cea1a5"},"_deposit":{"created_by":3,"id":"828","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"828"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00000828","sets":["11:12:16"]},"author_link":["3936","3934","49959","7928","3932","3939","551","3933"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1982-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"1032","bibliographicPageStart":"1028","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"井原, 良訓"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"上原, 章"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"土屋, 亮吉"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"久野, 栄進"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Thermal reactions of the [Ni(H2O)2(AA)2]X2·nH2O complexes in a solid phase were investigated, where AA is N,N′-diethylethylenediamine (NN′-deen), N,N-dimethylethylenediamine (NN-dmen), or N,N′-dimethylethylenediamine (NN′-dmen), and where X− is Cl−, Br−, I−, NO3− or ClO4−. By means of thermal analyses and spectral and magnetic measurements in a series of these complexes before and after heating, the following results were obtained. In the case of the NN′-deen complexes, only the perchlorate deaquates to change from octahedral to square-planar, but the other salts, such as the chloride, bromide, iodide, and nitrate, undergo deaquation-anation keeping their octahedral configuration. The deaquation-anation was also observed in the chloride, bromide, and nitrate of the NN-dmen complexes, but the iodide deaquated, and so was transformed from octahedral to square-planar. In the NN′-dmen complexes, only deaquation-anation was detected, irrespective of the anions (Cl−, Br−, I−, and NO3−). The effects of N-substituents in the diamines and the anions on the above transformation were discussed.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会＝The Chemical Society of Japan"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.55.1028","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/article/bcsj1926/55/4/55_4_1028/_article","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 日本化学会 The Chemical Society of Japan｜許可を得て登録"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12026255","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ihara, Yoshinori"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Izumi, Eiichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Uehara, Akira"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Tsuchiya, Ryokichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakagawa, Shigeo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kyuno, Eishin"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-02"}],"displaytype":"detail","filename":"LE-PR-IHARA-Y-1028-1032.pdf","filesize":[{"value":"381.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"LE-PR-IHARA-Y-1028-1032.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/828/files/LE-PR-IHARA-Y-1028-1032.pdf"},"version_id":"8e295900-fff3-4f0d-b17b-4abab1512b5e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase"}]},"item_type_id":"4","owner":"3","path":["16"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-02"},"publish_date":"2017-10-02","publish_status":"0","recid":"828","relation_version_is_last":true,"title":["Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T12:15:57.099348+00:00"}