{"created":"2023-07-27T06:19:50.248078+00:00","id":829,"links":{},"metadata":{"_buckets":{"deposit":"61f5ac00-adc4-419b-b3ef-ec8556bb257e"},"_deposit":{"created_by":3,"id":"829","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"829"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00000829","sets":["11:12:16"]},"author_link":["49959","54","3941","3942","551","3932"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1991-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"3652","bibliographicPageStart":"3647","bibliographicVolumeNumber":"64","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"井原, 良訓"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"鈴木, 正樹"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"上原, 章"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The thermochemical changes in coordination structure of diaquabis(N,N- or N,N′,-dialkylethylenediamine)nickel(II) complexes ([Ni(H2O)2(diamine)2]X2·nH2O) were reinvestigated by means of TG-DTA and electronic spectroscopy at room and elevated temperatures, where diamine is N,N (or N,N′-dimethylethylenediamine (NN- or NN′-dmen) or N,N-(or N,N′)-diethylethylenediamine (NN- or NN′-deen); X is Cl−, Br−, I−, or NO3−; n is 0, 1, 2, or 3. The diaqua complexes prepared were all trans except for cis-[Ni(H2O)2(NN-dmen)2]I2. The trans complexes with the symmetric (N,N′-dialkylsubstituted) diamines brought about a deaquation-anation upon heating, retaining the original trans configuration, while those with the asymmetric (N,N-dialkylsubstituted) diamines transformed into the cis complexes. In the case of the NN-dmen complexes, cis-halogenoaqua species were isolated as a stable intermediate during the thermal reactions. The complex nitrates changed to trans-dinitrato or cis-mononitrato species depending upon the diamines. The effects of the N-substituents in the diamines and of the anions on the patterns of thermal reactions were also discussed.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会＝The Chemical Society of Japan"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.64.3647","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/article/bcsj1926/64/12/64_12_3647/_article","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 日本化学会 The Chemical Society of Japan｜許可を得て登録"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12026255","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ihara, Yoshinori"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Satake, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Suzuki, Masatatsu"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Uehara, Akira"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-02"}],"displaytype":"detail","filename":"LE-PR-IHARA-Y-3647-3652.pdf","filesize":[{"value":"433.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"LE-PR-IHARA-Y-3647-3652.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/829/files/LE-PR-IHARA-Y-3647-3652.pdf"},"version_id":"dd345182-afb1-40a2-8ff0-195507dea107"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Cis-Trans Isomerism among the Octahedral Diaquabis(N,N- or N,N′-dialkylethylenediamine)nickel(II) Complexes and Their Thermal Reaction Products","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Cis-Trans Isomerism among the Octahedral Diaquabis(N,N- or N,N′-dialkylethylenediamine)nickel(II) Complexes and Their Thermal Reaction Products"}]},"item_type_id":"4","owner":"3","path":["16"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-02"},"publish_date":"2017-10-02","publish_status":"0","recid":"829","relation_version_is_last":true,"title":["Cis-Trans Isomerism among the Octahedral Diaquabis(N,N- or N,N′-dialkylethylenediamine)nickel(II) Complexes and Their Thermal Reaction Products"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T12:16:30.052427+00:00"}