{"created":"2023-07-27T06:25:08.100166+00:00","id":8309,"links":{},"metadata":{"_buckets":{"deposit":"f66c974b-4c78-460e-8cc1-d26a88943581"},"_deposit":{"created_by":3,"id":"8309","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"8309"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00008309","sets":["934:935:936"]},"author_link":["11586","11585","9808"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1989-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"728","bibliographicPageStart":"725","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"Analytical Sciences"}]}]},"item_4_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"4-(2-Thiazolylazo)-6-bromoresorcinol (TAR-Br) was synthesized and its usefulness for spectrophotometric determina¬tion of 14 lanthanoid(lll) ions was examined. The acid dissociation constants of the reagent and the stability constants of the complexes (1:1) were determined, and the complexing behavior was studied. The optimum pH for complexation lies between 6.8 – 8.7. Beer's law holds up to about 2.5 ppm of each lanthanoid, with a molar absorptivity of bxlOUmol−1 cm−1 level near 553 nm. The addition of ethanol produced some sensitization effect, due to solvation with the complexes. Both the molor absorptivities and the stability constants were larger in light lanthanoids with the atomic number, but the latter were slightly lower in heavy lanthanoids. TAR-Br was classified as a second ligand group member according to the Moeller's type classification. © 1989, The Japan Society for Analytical Chemistry. All rights reserved.","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Japan Society for Analytical Chemistry = 日本分析化学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.2116/analsci.5.725","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.jsac.jp/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/analsci","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © The Japan Society for Analytical Chemistry 日本分析化学会"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0910-6340","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ueda, Kazumasa"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Matsuda, Hideaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshimura, Osamu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-UEDA-K-725.pdf","filesize":[{"value":"215.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-UEDA-K-725.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/8309/files/SC-PR-UEDA-K-725.pdf"},"version_id":"78ed176b-889e-43d3-9595-d7d9fb96a0bf"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Complexation of Lanthanoids with 4-(2-Thiazolylazo)-6-bromoresorcinol","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Complexation of Lanthanoids with 4-(2-Thiazolylazo)-6-bromoresorcinol"}]},"item_type_id":"4","owner":"3","path":["936"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"8309","relation_version_is_last":true,"title":["Complexation of Lanthanoids with 4-(2-Thiazolylazo)-6-bromoresorcinol"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T02:10:48.543467+00:00"}