{"created":"2023-07-27T06:19:51.198834+00:00","id":852,"links":{},"metadata":{"_buckets":{"deposit":"aadffdfb-3140-43e0-aaad-62513f991962"},"_deposit":{"created_by":3,"id":"852","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"852"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00000852","sets":["11:12:16"]},"author_link":["49959","54","3941","3968","3942","3969","551","3932"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1991-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"2352","bibliographicPageStart":"2349","bibliographicVolumeNumber":"64","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"井原, 良訓"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"鈴木, 正樹"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"上原, 章"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The structures of two diaquabis(N,N-dialkylethylenediamine)nickel(II) chlorides ([Ni(H2O)2(diamine)2]Cl2·nH2O) were determined by X-ray crystallographic studies, where diamine is N,N-dimethylethylenediamine(NN-dmen) or N,N-diethylethylenediamine (NN-deen). Both complexes are trans and crystallize in the monoclinic space group P21⁄n. The unit cell parameters of the NN-dmen complex, NiCl2C8N4O2H32, are a=7.531(1), b=13.092(1), c=9.591 Å, β=107.76(1)°, and Z=2, and those of the NN-deen complex, NiCl2C12N4O2H36, are a=9.154(1), b=8.692(1), c=12.395(2) Å, β=104.46(1)°, and Z=2. In trans-[Ni(H2O)2(NN-dmen)2]Cl2·2H2O and trans-[Ni(H2O)2(NN-deen)2]Cl2, the Ni–NMe2 and Ni–NEt2 bond distances (2.183 and 2.271 Å) are much longer than the Ni–NH2 distances (2.078 and 2.064 Å), forming tetragonally distorted octahedrons with four close in-plane neighbors(N2O2) and two remote axial ones(N2). It is apparent that this distortion originates from the steric requirement of N-substituted groups. Such a distortion significantly affects the electronic spectra of these complexes.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会＝The Chemical Society of Japan"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.64.2349","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/article/bcsj1926/64/8/64_8_2349/_article","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 日本化学会 The Chemical Society of Japan｜許可を得て登録"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12026255","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ihara, Yoshinori"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Satake, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujimoto, Yumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Senda, Hitoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Suzuki, Masatatsu"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Uehara, Akira"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-02"}],"displaytype":"detail","filename":"LE-PR-IHARA-Y-2349-2352.pdf","filesize":[{"value":"304.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"LE-PR-IHARA-Y-2349-2352.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/852/files/LE-PR-IHARA-Y-2349-2352.pdf"},"version_id":"71fa4cec-1b60-42a5-bc20-3da9ce07c2ac"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"X-Ray Crystal Structures of Octahedral Diaquabis(N,N-dialkyl-ethylenediamine)nickel(II) Complexes Possessing Elongated Nickel(II)–Nitrogen Bonds along Axial Direction","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"X-Ray Crystal Structures of Octahedral Diaquabis(N,N-dialkyl-ethylenediamine)nickel(II) Complexes Possessing Elongated Nickel(II)–Nitrogen Bonds along Axial Direction"}]},"item_type_id":"4","owner":"3","path":["16"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-02"},"publish_date":"2017-10-02","publish_status":"0","recid":"852","relation_version_is_last":true,"title":["X-Ray Crystal Structures of Octahedral Diaquabis(N,N-dialkyl-ethylenediamine)nickel(II) Complexes Possessing Elongated Nickel(II)–Nitrogen Bonds along Axial Direction"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T12:16:28.946262+00:00"}