{"created":"2023-07-27T06:25:43.234024+00:00","id":9134,"links":{},"metadata":{"_buckets":{"deposit":"bdf58626-1e69-4bac-8628-102a39db1852"},"_deposit":{"created_by":3,"id":"9134","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"9134"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00009134","sets":["934:935:936"]},"author_link":["13005","540","13004","9840"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1997-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"1067","bibliographicPageStart":"1061","bibliographicVolumeNumber":"70","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A poly[1-methyl-3-(pyrrol-1-ylmethyl)pyridinium] perchlorate-coated glassy carbon electrode noticeably decreased the charge-transfer resistance (Rt) of quinhydrone relative to a naked glassy carbon electrode. The redox species was not concentrated into a polymer film; this result differs markedly from the very good absorption of anthraquinonesulfonates and indigosulfonates by a polymer film. The dependence of Rt and the interfacial capacitance on the film thickness implies that the charge-transfer process occurs at the film-solution interface, because the polymer film is appreciably electronically conductive at positive potentials. Because of a change in the film conductivities with the potential, the polymer-coated electrode increased the anodic peak current of quinhydrone by three times, but decreased its cathodic peak current by two fifths, relative to that of a naked electrode. Although the decrease in Rt at a polymer-film electrode is somewhat ascribed to an increasing area, which is due to a porous film surface, the electrocatalytic effect of the polymer film can be attributed to an increasing standard rate constant of the charge-transfer process; this increase may be due to the adsorption of quinhydrone on the polymer surface.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"ktakaha@se.kanazawa-u.ac.jp","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Chemical Society of Japan = 日本化学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.70.1061","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/bcsj","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © The Chemical Society of Japan 日本化学会"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Komura, Teruhisa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kobayashi, Tomohiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamaguchi, Takahiro"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Takahashi, Koshin"}],"nameIdentifiers":[{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"TE-PR-TAKAHASHI-K-1061.pdf","filesize":[{"value":"1.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TE-PR-TAKAHASHI-K-1061.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/9134/files/TE-PR-TAKAHASHI-K-1061.pdf"},"version_id":"4bbb78d6-073a-4f98-bdf2-be5de35f9b56"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Increased redox-reaction rate of quinhydrone at N-substituted polypyrrole film electrodes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Increased redox-reaction rate of quinhydrone at N-substituted polypyrrole film electrodes"}]},"item_type_id":"4","owner":"3","path":["936"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"9134","relation_version_is_last":true,"title":["Increased redox-reaction rate of quinhydrone at N-substituted polypyrrole film electrodes"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T01:58:30.074776+00:00"}