{"created":"2023-07-27T06:26:08.414748+00:00","id":9734,"links":{},"metadata":{"_buckets":{"deposit":"fcdf2d9d-63b7-4f86-b75e-2bc2f36b6a13"},"_deposit":{"created_by":3,"id":"9734","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"9734"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00009734","sets":["934:935:936"]},"author_link":["2665","9840","14197","14198","99528","540","11325"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageStart":"124513","bibliographicVolumeNumber":"105","bibliographic_titles":[{"bibliographic_title":"Journal of Applied Physics"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"桑原, 貴之"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"山口, 孝浩"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"高橋, 光信"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A fluorine-doped tin oxide (FTO)/zinc sulfide (ZnS)/[6,6]-phenyl C 61 butyric acid methyl ester (PCBM): regioregular poly(3-hexylthiophene) P3HT)/poly(3,4-ethylenedioxylenethiophene): poly(4-styrene sulfonic acid) (PEDOT:PSS)/Au type organic solar cell (FTO/ZnS/PCBM:P3HT/PEDOT:PSS/Au, ZnS cell) with a 1 cm2 active area was first developed using transparent ZnS prepared on a FTO electrode by a chemical bath deposition method. The ZnS inserted solar cells were investigated by photocurrent-voltage (I-V) and ac impedance spectroscopy (IS) measurements. In photo I-V measurements, the ZnS cell exhibited scattered power conversion efficiencies (η) of 0.7%-1.2% when the FTO/ZnS electrode was not immersed in various aqueous solutions before the fabrication of the ZnS cells. In contrast, the solar cells with a surface-modified FTO/ZnS electrode by immersing in 0.1M Na2 S solutions at pH 7-9 containing hydrosulfide ions (HS-) exhibited reproducible η of 1.5%-1.7%. The electric resistance components in the cell consisting of five layers were separately estimated by the IS measurement. The larger of the solar cell using HS- modified ZnS was explained by the fact that the charge transport resistance at the ZnS/PCBM:P3HT interface became smaller due to this surface modification. When a continuous light irradiation was carried out for the modified cells, the resistance at the ZnS/PCBM:P3HT interface increased, being accompanied by the decrease in the η. That is, the cell performance was controlled mainly by charge transport velocity at the ZnS/PCBM:P3HT interface. © 2009 American Institute of Physics.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00009721","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Institute of Physics"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1063/1.3153970","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00693547","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-8979","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kuwabara, Takayuki"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Nakamoto, Masayuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawahara, Yoshitaka"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamaguchi, Takahiro"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Takahashi, Kohshin"}],"nameIdentifiers":[{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"TE-PR-KUWABARA-T-124513.pdf","filesize":[{"value":"557.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"TE-PR-KUWABARA-T-124513.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/9734/files/TE-PR-KUWABARA-T-124513.pdf"},"version_id":"9b86688f-cddb-4bf9-805c-567617893225"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Characterization of ZnS-layer-inserted bulk-heterojunction organic solar cells by ac impedance spectroscopy","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Characterization of ZnS-layer-inserted bulk-heterojunction organic solar cells by ac impedance spectroscopy"}]},"item_type_id":"4","owner":"3","path":["936"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"9734","relation_version_is_last":true,"title":["Characterization of ZnS-layer-inserted bulk-heterojunction organic solar cells by ac impedance spectroscopy"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T10:29:10.362566+00:00"}