{"created":"2023-07-27T06:26:12.080383+00:00","id":9820,"links":{},"metadata":{"_buckets":{"deposit":"963cea35-d221-4825-978f-337ef9c9b29d"},"_deposit":{"created_by":3,"id":"9820","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"9820"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00009820","sets":["934:935:936"]},"author_link":["14388","14392","14387","14390","14389","3945","14391"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-10-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10-12","bibliographicPageEnd":"1243","bibliographicPageStart":"1239","bibliographicVolumeNumber":"77","bibliographic_titles":[{"bibliographic_title":"Radiation Physics and Chemistry"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We examined formation of solvated electrons in several ionic liquids composed of ammonium, pyrrolidinium and piperidinium cations by observing absorption spectra in the visible and near-infrared regions using pulse radiolysi. We also examined reactions of the solvated electrons with imidazolium cations in the ionic liquids. The reaction rate constants were an order of magnitude faster than the diffusion-limited rate calculated from the viscosity. The electrons before full solvation (dry electrons) reacted efficiently with the imidazolium cations. These observations suggest that the electrons in the ionic liquids can move easily before solvation. The scavenging of the dry electron by the imidazolium cation was also examined using C2-alkylated-imidazolium cations. It is found that the alkylation of imidazolium suppresses the reactivity with the dry electron. © 2008 Elsevier Ltd. All rights reserved.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域自然システム学系","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.radphyschem.2008.05.042","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.elsevier.com/locate/issn/0969806X","subitem_relation_type_select":"URI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA10867451","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0969-806X","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takahashi, Kenji"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Sato, Toshifumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Katsumura, Yosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yang, Jinfeng"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kondo, Takafumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshida, Yoichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Katoh, Ryuzi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"TE-PR-TAKAHASHI-K-1239.pdf","filesize":[{"value":"435.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TE-PR-TAKAHASHI-K-1239.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/9820/files/TE-PR-TAKAHASHI-K-1239.pdf"},"version_id":"ba84b9f2-605b-4ffc-be03-2633c597b19d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reactions of solvated electrons with imidazolium cations in ionic liquids","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reactions of solvated electrons with imidazolium cations in ionic liquids"}]},"item_type_id":"4","owner":"3","path":["936"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"9820","relation_version_is_last":true,"title":["Reactions of solvated electrons with imidazolium cations in ionic liquids"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T01:48:37.801457+00:00"}