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Thermal Square Planar-to-octahedral Transformation of Nickel(II) Complexes Containing 1,2-Diphenyl-1,2-ethanediamine in the Solid Phase
http://hdl.handle.net/2297/37508
http://hdl.handle.net/2297/375082d78058a-1704-4868-a334-e3113a3ea5c2
名前 / ファイル | ライセンス | アクション |
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LE-PR-IHARA-Y-2829-2831.pdf (234.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-02 | |||||
タイトル | ||||||
タイトル | Thermal Square Planar-to-octahedral Transformation of Nickel(II) Complexes Containing 1,2-Diphenyl-1,2-ethanediamine in the Solid Phase | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ihara, Yoshinori
× Ihara, Yoshinori× Tsuchiya, Ryokichi |
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著者別表示 |
井原, 良訓
× 井原, 良訓× 土屋, 亮吉 |
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書誌情報 |
Bulletin of the Chemical Society of Japan 巻 57, 号 10, p. 2829-2831, 発行日 1984-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2673 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12026255 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/bcsj.57.2829 | |||||
出版者 | ||||||
出版者 | 日本化学会=The Chemicai Society of Japan | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The following ten nickel(II) complexes with meso- or dl-1,2-diphenyl-1,2-ethanediamine (abbreviated as meso-stien and dl-stien, respectively) were prepared, and their thermal behavior was investigated in the solid phase: [Ni(meso-stien)2]X2 (X=Cl, Br, I, NO3, or ClO4), [Ni(dl-stien)2]X2 (X=I or ClO4), and [Ni(H2O)2(dl-stien)2]X2 (X=Cl, Br, or NO3). The square planar bis(dl-stien) complex chloride, bromide, and nitrate obtained by thermal dehydration of their respective octahedral diaqua complexes were found by various techniques to be transformed, upon further heating, to the octahedral diacido bis(dl-stien) complexes. The complexes containing dl-stien have a stronger tendency to show such structural transformations than those containing meso-stien. The reason for this difference is discussed. | |||||
権利 | ||||||
権利情報 | Copyright © 日本化学会 The Chemicai Society of Japan|許可を得て登録 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.chemistry.or.jp/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/article/bcsj1926/57/10/57_10_2829/_article |