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二核鉄ペルオキソ錯体のコア構造による反応性の制御
https://doi.org/10.24517/00052466
https://doi.org/10.24517/000524660ec1a320-df61-4155-a2f3-be76c674e783
名前 / ファイル | ライセンス | アクション |
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SC-PR-FURUTACHI-H-kaken 2017-5p.pdf (1.2 MB)
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Item type | 報告書 / Research Paper(1) | |||||
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公開日 | 2018-10-15 | |||||
タイトル | ||||||
タイトル | 二核鉄ペルオキソ錯体のコア構造による反応性の制御 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Control of oxidation reactivity of (peroxo)diiron complexes | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_18ws | |||||
資源タイプ | research report | |||||
ID登録 | ||||||
ID登録 | 10.24517/00052466 | |||||
ID登録タイプ | JaLC | |||||
著者別表示 |
Furutachi, Hideki
× Furutachi, Hideki |
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提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学理工研究域物質化学系 | |||||
書誌情報 |
平成28(2016)年度 科学研究費補助金 基盤研究(C) 研究成果報告書 en : 2016 Fiscal Year Final Research Report 巻 2014-04-01 - 2017-03-31, p. 5p., 発行日 2017-06-02 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 生体系では,メタンモノオキシゲナーゼ(MMO) や トルエンモノオキシゲナーゼ(TMO)が二核鉄中心により酸素分子を活性化して,アルカンやアレーン類の水酸化をいとも簡単に行っている.本研究では,MMOやTMOのペルオキソ中間体の機能モデルとなる二核鉄(III)ペルオキソ錯体を創製し,コア構造によるペルオキソ錯体の反応性の制御を目指して,外部基質との酸化反応性の検討を行った. | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The Fe2/O2-mediated oxidation reactions such as arene hydroxylation and C-H bond oxidation of alkanes are of current interest for understanding the reaction mechanism of dioxygen activating non-heme diiron enzymes such as soluble methane monooxygenase (sMMO) and toluene monooxygenase (TMO) and utilizing metal complexes as oxidation catalysis. Various synthetic (peroxo)diiron(III) model complexes have been developed, however, there are few functional models that exhibit oxidation reactivity and O-O bond cleavage similar to those of (peroxo)diiron(III) species in non-heme diiron enzymes. In this study, (peroxo)diiron(III) complexes having a bridging ligand (oxo or carboxylate) were prepared and their oxidation reacvtivities towards external substrates were studied. We found a mechanistic evidence that a diiron(IV)-oxo species derived from the O-O bond cleavage of (peroxo)diiron(III) species is involved in the oxidation reaction as an active oxidant. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 研究課題/領域番号:26410067, 研究期間(年度):2014-04-01 - 2017-03-31 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 出典:「二核鉄ペルオキソ錯体のコア構造による反応性の制御」研究成果報告書 課題番号26410067 (KAKEN:科学研究費助成事業データベース(国立情報学研究所)) (https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26410067/26410067seika/)を加工して作成 |
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著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/search/?qm=40332663 | |||||
関連名称 | https://kaken.nii.ac.jp/search/?qm=40332663 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26410067/ | |||||
関連名称 | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26410067/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26410067/26410067seika/ | |||||
関連名称 | https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-26410067/26410067seika/ |