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Hetero and lacunary polyoxovanadate chemistry: Synthesis, reactivity and structural aspects
http://hdl.handle.net/2297/29199
http://hdl.handle.net/2297/291998d0a8e0e-cd67-431f-9cfb-f25e622a4ba4
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-HAYASHI-Y-2270.pdf (801.4 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-10-03 | |||||
| タイトル | ||||||
| タイトル | Hetero and lacunary polyoxovanadate chemistry: Synthesis, reactivity and structural aspects | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Hayashi, Yoshihito
× Hayashi, Yoshihito |
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| 書誌情報 |
Coordination Chemistry Reviews 巻 255, 号 19-20, p. 2270-2080, 発行日 2011-10-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0010-8545 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00619249 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.ccr.2011.02.013 | |||||
| 出版者 | ||||||
| 出版者 | Elsevier B.V. | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Many synthetic methods for heteropolyoxovanadates and lacunary polyoxovanadates have been developed in recent years. We outline various approaches used to produce new polyoxovanadate species, including heterometal-incorporated complexes of tetravanadates, hexavanadates, decavanadates and dodecavanadates. In particular, three types of synthetic routes are explored; based on (i) coordination of metavanadate species to transition metal cations, (ii) oxidation of reduced polyoxovanadates, and (iii) template synthesis. Metavanadate species can coordinate to metal cations as inorganic macrocyclic ligands to form heteropolyoxovanadates. The incorporation of a heterometal cation into decavanadates has also been reported. The oxidation reaction of reduced polyoxovanadates provides a new route to the formation of the lacunary polyoxovanadates, which can serve as inorganic host molecules. Dodecavanadates are bowl-type molecules of particular structural interest; a chloride anion can be incorporated into the bowl through a template synthesis. Structural transformations between these dodecavanadate species and alkoxopolyoxovanadates are also described. © 2011 Elsevier B.V. | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 関連URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.elsevier.com/locate/issn/00108545 | |||||
