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イオンクロマトグラフィーにおける保持挙動の解析に関する研究
http://hdl.handle.net/2297/25009
http://hdl.handle.net/2297/25009452b6229-13bf-4962-b58c-c2d565333880
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-HIRAYAMA-N-255.pdf (172.3 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-10-03 | |||||
| タイトル | ||||||
| タイトル | イオンクロマトグラフィーにおける保持挙動の解析に関する研究 | |||||
| タイトル | ||||||
| タイトル | A study on analysis of retention behavior in ion chromatography | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
平山, 直樹
× 平山, 直樹 |
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| 提供者所属 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 金沢大学理工研究域 | |||||
| 書誌情報 |
分析化学 = Japan analyst 巻 43, 号 3, p. 255-256, 発行日 1994-03-05 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0525-1931 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00222633 | |||||
| 出版者 | ||||||
| 出版者 | The Japan Society for Analytical Chemistry = 日本分析化学会 | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Relationships between ion-chromatographic retention behaviors of several anions and their dissociation constants were studied from two standpoints. In Part 1,the influence of the dissociation equilibria on the measured capacity factor of a sample was interpreted. In this study, the ratio of the capacity factor of the sample to that of a standard anion was used for the analysis of the retention behavior. The dissociation constants and the ratio of the capacity factors of various species of the sample to that of the standard were calculated and the retention behavior was estimated. In Part 2,the differences in the retention times of substituted benzoate anions having similar structure were analyzed by dividing the substituent effect into an LFER-applicable effect term, a steric effect term and a positional effect correction term. The first was introduced by putting the theory of linear free energy relationships into the relationship between the anion-exchange equilibria and the dissociation equilibria. The second depends on kind and number of the introduced substituents, and the last on the position of them. Furthermore, the estimation of the retention times of these anions and the determination of the dissociation constants of substituted naphthoic acids were done. | |||||
| 権利 | ||||||
| 権利情報 | Copyright (c) 1994 日本分析化学会 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 関連URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.jsac.or.jp/index.html | |||||
| 関連URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://ci.nii.ac.jp/naid/110002906749/en/ | |||||
