WEKO3
インデックスリンク
アイテム
{"_buckets": {"deposit": "5b110518-b9fa-48df-9f07-94eabdbd51f7"}, "_deposit": {"created_by": 3, "id": "15244", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "15244"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00015244", "sets": ["1135"]}, "author_link": ["288", "27552", "27550", "27551", "604", "27549"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2003-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "x6", "bibliographicPageStart": "x5", "bibliographicVolumeNumber": "19", "bibliographic_titles": [{"bibliographic_title": "Analytical Sciences: X-ray Structure Analysis Online"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Crystal structure of 4-N,N-dimethylamino-2,3,5,6-tetrafluorobenzonitrile (4F-DMABN) has been determined by X-ray diffraction. This compound crystallizes in the monoclinic system, space group P21/c, with unit cell parameters: a = 4.373(2)Å, b = 10.654(6)Å, c = 20.05(1)Å, β = 92.92(2)°, Z = 4, V = 933.2(9)Å3. The crystal structure was solved by direct methods and refined by full-matrix least squares to final values of R = 0.082 and Rw = 0.089 with 1129 reflections (I\u003e1.20σ(I)). The dimethylamino group is out of the aromatic ring plane. The dihedral angle between the least-squares planes of the aromatic ring and the dimethylamino group is 32.73(5)°. The aromatic ring has a significant quinoid nature.", "subitem_description_type": "Abstract"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "日本分析化学会 = The Japan Society for Analytical Chemistry"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.2116/analscix.19.x5", "subitem_relation_type_select": "DOI"}}]}, "item_4_relation_28": {"attribute_name": "関連URI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://japanlinkcenter.org/JST.JSTAGE/analscix/19.x5", "subitem_relation_type_select": "URI"}}, {"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://wwwsoc.nii.ac.jp/jsac/", "subitem_relation_type_select": "URI"}}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright (c) 2003 by The Japan Society for Analytical Chemistry"}]}, "item_4_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1348-2238", "subitem_source_identifier_type": "ISSN"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nakagaki, Ryoichi"}], "nameIdentifiers": [{"nameIdentifier": "288", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20159057", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20159057"}, {"nameIdentifier": "20159057", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000020159057"}]}, {"creatorNames": [{"creatorName": "Kohtani, Shigeru"}], "nameIdentifiers": [{"nameIdentifier": "27549", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakamura, Yuko"}], "nameIdentifiers": [{"nameIdentifier": "27550", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okamura, Michiyo"}], "nameIdentifiers": [{"nameIdentifier": "27551", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kitoh, Sohichi"}], "nameIdentifiers": [{"nameIdentifier": "27552", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kunimoto, Koki"}], "nameIdentifiers": [{"nameIdentifier": "604", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "10242538", "nameIdentifierScheme": "金沢大学研究者情報", "nameIdentifierURI": "http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=10242538"}, {"nameIdentifier": "10242538", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000010242538"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-04"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PH-PR-NAKAGAKI-R-5.pdf", "filesize": [{"value": "67.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 67800.0, "url": {"label": "PH-PR-NAKAGAKI-R-5.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/15244/files/PH-PR-NAKAGAKI-R-5.pdf"}, "version_id": "87f25cee-abc7-437c-a09d-f1b2bef0b1d1"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Crystal Structure of 4-N,N-Dimethylamino-2,3,5,6-tetrafluorobenzonitrile", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Crystal Structure of 4-N,N-Dimethylamino-2,3,5,6-tetrafluorobenzonitrile"}]}, "item_type_id": "4", "owner": "3", "path": ["1135"], "permalink_uri": "http://hdl.handle.net/2297/28462", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-04"}, "publish_date": "2017-10-04", "publish_status": "0", "recid": "15244", "relation": {}, "relation_version_is_last": true, "title": ["Crystal Structure of 4-N,N-Dimethylamino-2,3,5,6-tetrafluorobenzonitrile"], "weko_shared_id": -1}
Crystal Structure of 4-N,N-Dimethylamino-2,3,5,6-tetrafluorobenzonitrile
http://hdl.handle.net/2297/28462
http://hdl.handle.net/2297/28462a2f8986a-4908-43d9-adba-9b4e9bc70f16
名前 / ファイル | ライセンス | アクション |
---|---|---|
PH-PR-NAKAGAKI-R-5.pdf (67.8 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2017-10-04 | |||||
タイトル | ||||||
タイトル | Crystal Structure of 4-N,N-Dimethylamino-2,3,5,6-tetrafluorobenzonitrile | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Nakagaki, Ryoichi
× Nakagaki, Ryoichi× Kohtani, Shigeru× Nakamura, Yuko× Okamura, Michiyo× Kitoh, Sohichi× Kunimoto, Koki |
|||||
書誌情報 |
Analytical Sciences: X-ray Structure Analysis Online 巻 19, p. x5-x6, 発行日 2003-01-01 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1348-2238 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.2116/analscix.19.x5 | |||||
出版者 | ||||||
出版者 | 日本分析化学会 = The Japan Society for Analytical Chemistry | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Crystal structure of 4-N,N-dimethylamino-2,3,5,6-tetrafluorobenzonitrile (4F-DMABN) has been determined by X-ray diffraction. This compound crystallizes in the monoclinic system, space group P21/c, with unit cell parameters: a = 4.373(2)Å, b = 10.654(6)Å, c = 20.05(1)Å, β = 92.92(2)°, Z = 4, V = 933.2(9)Å3. The crystal structure was solved by direct methods and refined by full-matrix least squares to final values of R = 0.082 and Rw = 0.089 with 1129 reflections (I>1.20σ(I)). The dimethylamino group is out of the aromatic ring plane. The dihedral angle between the least-squares planes of the aromatic ring and the dimethylamino group is 32.73(5)°. The aromatic ring has a significant quinoid nature. | |||||
権利 | ||||||
権利情報 | Copyright (c) 2003 by The Japan Society for Analytical Chemistry | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://japanlinkcenter.org/JST.JSTAGE/analscix/19.x5 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://wwwsoc.nii.ac.jp/jsac/ |