WEKO3
インデックスリンク
アイテム
Stability and mode of coordination complexes formed in the silver(i)/nucleoside systems
http://hdl.handle.net/2297/29304
http://hdl.handle.net/2297/2930487886cd4-a381-48b7-8fce-2ae3c5867454
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
PH-PR-ODANI-A-1672.pdf (515.2 kB)
|
|
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-10-04 | |||||
| タイトル | ||||||
| タイトル | Stability and mode of coordination complexes formed in the silver(i)/nucleoside systems | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Odani, Akira
× Odani, Akira× Jastrzab, Renata× Lomozik, Lechoslaw |
|||||
| 書誌情報 |
New Journal of Chemistry 巻 35, 号 8, p. 1672-1677, 発行日 2011-08-01 |
|||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1144-0546 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA10686388 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1039/c1nj20230h | |||||
| 出版者 | ||||||
| 出版者 | Royal Society of Chemistry | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Complexes of silver(i) with nucleosides (adenosine, cytidine, uridine and thymidine) have been studied using potentiometric, spectral and theoretical methods. Stability constants of the complexes as well as their coordination modes have been determined. Results of the equilibrium studies have provided evidence for the formation of only ML and ML(OH) type complexes. The basicity of nucleosides was found to substantially influence the stability constant of the ML type complexes. Spectral data have allowed us to identify the sites of silver attachment to the nucleoside. Additionally a new silver-adenosine complex of stoichiometry Ag(Ado)(OH) was prepared from aqueous solution at pH close to 6. Its characterization and comparison with complexes formed in solution are described. The structures of complexes formed in solution and in solid state were confirmed through computational calculations (DFT/B3LYP: lanL2DZ theoretical procedure). © 2011 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
