WEKO3
インデックスリンク
アイテム
Fourier transformation microwave spectroscopy of the methyl glycolate-H2O complex
https://doi.org/10.24517/00049638
https://doi.org/10.24517/00049638b50eb731-5a69-40b5-80c4-59e4f6a845dd
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-FUJITAKE-M-3.pdf (1.6 MB)
|
.png)
|
| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2017-12-28 | |||||||||
| タイトル | ||||||||||
| タイトル | Fourier transformation microwave spectroscopy of the methyl glycolate-H2O complex | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| ID登録 | ||||||||||
| ID登録 | 10.24517/00049638 | |||||||||
| ID登録タイプ | JaLC | |||||||||
| 著者 |
Fujitake, Masaharu
× Fujitake, Masaharu× Tanaka, Toshihiro× Ohashi, Nobukimi |
|||||||||
| 著者別表示 |
藤竹, 正晴
× 藤竹, 正晴
× 大橋, 信喜美
|
|||||||||
| 提供者所属 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | 金沢大学理工研究域数物科学系 | |||||||||
| 書誌情報 |
Journal of Molecular Spectroscopy 巻 343, p. 3-17, 発行日 2018-01-01 |
|||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 0022-2852 | |||||||||
| NCID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AA00702841 | |||||||||
| DOI | ||||||||||
| 関連タイプ | isVersionOf | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.1016/j.jms.2017.09.011 | |||||||||
| 出版者 | ||||||||||
| 出版者 | Academic Press / Elsevier | |||||||||
| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | The rotational spectrum of one conformer of the methyl glycolate-H2O complex has been measured by means of the pulsed jet Fourier transform microwave spectrometer. The observed a- and b-type transitions exhibit doublet splittings due to the internal rotation of the methyl group. On the other hand, most of the c-type transitions exhibit quartet splittings arising from the methyl internal rotation and the inversion motion between two equivalent conformations. The spectrum was analyzed using parameterized expressions of the Hamiltonian matrix elements derived by applying the tunneling matrix formalism. Based on the results obtained from ab initio calculation, the observed complex of methyl glycolate-H2O was assigned to the most stable conformer of the insertion complex, in which a non-planer seven membered-ring structure is formed by the intermolecular hydrogen bonds between methyl glycolate and H2O subunits. The inversion motion observed in the c-type transitions is therefore a kind of ring-inversion motion between two equivalent conformations. Conformational flexibility, which corresponds to the ring-inversion between two equivalent conformations and to the isomerization between two possible conformers of the insertion complex, was investigated with the help of the ab initio calculation. © 2017 Elsevier Inc. | |||||||||
| 内容記述 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | Embargo Period 24 months | |||||||||
| 権利 | ||||||||||
| 権利情報 | Copyright © Academic Press / Elsevier (CC-BY NC ND) | |||||||||
| 著者版フラグ | ||||||||||
| 出版タイプ | AM | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||
| 関連URI | ||||||||||
| 識別子タイプ | URI | |||||||||
| 関連識別子 | http://www.elsevier.com/locate/issn/00222852 | |||||||||
| 関連名称 | http://www.elsevier.com/locate/issn/00222852 | |||||||||
