{"_buckets": {"deposit": "2199e37b-0504-4385-a39a-06510ae70c3c"}, "_deposit": {"created_by": 18, "id": "46545", "owners": [18], "pid": {"revision_id": 0, "type": "depid", "value": "46545"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00046545", "sets": ["2819"]}, "author_link": ["16409", "2433"], "item_9_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015-06-13", "bibliographicIssueDateType": "Issued"}, "bibliographicPageStart": "4p.", "bibliographicVolumeNumber": "2013-04-01 - 2015-03-31", "bibliographic_titles": [{"bibliographic_title": "平成26(2014)年度 科学研究費補助金 挑戦的萌芽研究 研究成果報告書"}, {"bibliographic_title": "2014 Fiscal Year Final Research Report", "bibliographic_titleLang": "en"}]}]}, "item_9_creator_33": {"attribute_name": "著者別表示", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Imura, Hisanori"}], "nameIdentifiers": [{"nameIdentifier": "16409", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60142923", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60142923"}]}]}, "item_9_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "天然配位子ヒノキチオール（Hipt）およびその類縁体として一連のβ-ジケトン，補助錯形成剤として，疎水性の高い4,7-ジフェニル-1,10-フェナントロリン(dpp)やトリオクチルホスフィンオキシド等を用いて，ランタノイドイオン（Ln）の新規な協同効果抽出を研究した。抽出溶媒として極性の高いo-ジクロロベンゼン（DCB）あるいはイミダゾリウム系イオン液体を用いると，Lnはカチオン性三元錯体として抽出され，重希土選択的な協同効果が発現することが分かった。また，Hipt-dpp-DCB支持液体膜を用いて，Lnの膜輸送の律速段階を明らかにし，NdとDyなどの分離に適用できることを示した。", "subitem_description_type": "Abstract"}, {"subitem_description": "Novel synergistic extraction of lanthanoid(III) ions (Ln) with hinokitiol (Hipt) or β-diketones as an acidic chelating agent was studied in the presence of a hydrophobic neutral ligand such as 4,7-diphenyl-1,10-phenanthroline (dpp) and trioctylphosphine oxide (TOPO). When 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide was used as the extracting solvent, the extraction of heavier Ln with acetylacetone and benzoylacetone in the presence of TOPO was remarkably enhanced, resulting in a significant improvement in the separation of Ln. The present synergism was caused by the formation of cationic ternary complexes followed by ion exchange into the ionic liquid. Similar cationic ternary complexes were also extracted with Hipt and dpp in o-dichlorobenzene. This synergistic extraction system was applied to the supported liquid membrane (SLM) transport of Ln. The heavier Ln was selectively transported through the SLM and concentrated into the acidic aqueous phase.", "subitem_description_type": "Abstract"}]}, "item_9_description_22": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "研究課題/領域番号:25620108, 研究期間(年度):2013-04-01 - 2015-03-31", "subitem_description_type": "Other"}, {"subitem_description": "出典：研究課題「天然配位子とイオン液体を用いるランタノイドの環境調和型高効率分離システム」課題番号25620108\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620108/25620108seika/)を加工して作成", "subitem_description_type": "Other"}]}, "item_9_description_5": {"attribute_name": "提供者所属", "attribute_value_mlt": [{"subitem_description": "金沢大学理工研究域物質化学系", "subitem_description_type": "Other"}]}, "item_9_identifier_registration": {"attribute_name": "ID登録", "attribute_value_mlt": [{"subitem_identifier_reg_text": "10.24517/00052877", "subitem_identifier_reg_type": "JaLC"}]}, "item_9_relation_28": {"attribute_name": "関連URI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "https://kaken.nii.ac.jp/search/?qm=60142923"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://kaken.nii.ac.jp/search/?qm=60142923", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620108/"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620108/", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620108/25620108seika/"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620108/25620108seika/", "subitem_relation_type_select": "URI"}}]}, "item_9_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "井村, 久則"}], "nameIdentifiers": [{"nameIdentifier": "2433", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60142923", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60142923"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-12-10"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "SC-PR-IMURA-H-kaken 2015-4p.pdf", "filesize": [{"value": "192.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_11", "mimetype": "application/pdf", "size": 192000.0, "url": {"label": "SC-PR-IMURA-H-kaken 2015-4p.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/46545/files/SC-PR-IMURA-H-kaken 2015-4p.pdf"}, "version_id": "538b4d99-b10a-4cf8-92fd-4d1d0af46561"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "溶媒抽出", "subitem_subject_scheme": "Other"}, {"subitem_subject": "液体膜分離", "subitem_subject_scheme": "Other"}, {"subitem_subject": "イオン液体", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ランタノイド", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "天然配位子とイオン液体を用いるランタノイドの環境調和型高効率分離システム", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "天然配位子とイオン液体を用いるランタノイドの環境調和型高効率分離システム"}, {"subitem_title": "Separation of lanthanoid ions by green extraction systems with natural ligand and ionic liquid", "subitem_title_language": "en"}]}, "item_type_id": "9", "owner": "18", "path": ["2819"], "permalink_uri": "https://doi.org/10.24517/00052877", "pubdate": {"attribute_name": "公開日", "attribute_value": "2018-12-10"}, "publish_date": "2018-12-10", "publish_status": "0", "recid": "46545", "relation": {}, "relation_version_is_last": true, "title": ["天然配位子とイオン液体を用いるランタノイドの環境調和型高効率分離システム"], "weko_shared_id": -1}