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Nickel-Catalyzed Cross-Electrophile Coupling between Benzyl Alcohols and Aryl Halides Assisted by Titanium Co-reductant
https://doi.org/10.24517/00053795
https://doi.org/10.24517/00053795f76dd65f-5134-4c10-bb65-aaef60b5efd8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-SUGA-T-7846.pdf (655.2 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||
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| 公開日 | 2019-04-01 | |||||||||
| タイトル | ||||||||||
| タイトル | Nickel-Catalyzed Cross-Electrophile Coupling between Benzyl Alcohols and Aryl Halides Assisted by Titanium Co-reductant | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| ID登録 | ||||||||||
| ID登録 | 10.24517/00053795 | |||||||||
| ID登録タイプ | JaLC | |||||||||
| 著者 |
Suga, Takuya
× Suga, Takuya× Ukaji, Yutaka |
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| 著者別表示 |
菅, 拓也
× 菅, 拓也
× 宇梶, 裕
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| 提供者所属 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | 金沢大学理工研究域物質化学系 | |||||||||
| 書誌情報 |
Organic Letters 巻 20, 号 4, p. 7846-7850, 発行日 2018-12-21 |
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| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 1523-7060 | |||||||||
| NCID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AA11347843 | |||||||||
| DOI | ||||||||||
| 関連タイプ | isVersionOf | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.1021/acs.orglett.8b03367 | |||||||||
| 出版者 | ||||||||||
| 出版者 | American Chemical Society | |||||||||
| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | A nickel-catalyzed cross-electrophile coupling reaction between benzyl alcohols and aryl halides has been developed using a homolytic C–O bond cleavage protocol that has recently been established. The treatment of a benzyl alcohol and aryl halide with a nickel catalyst and low-valent titanium reagent generated from TiCl4(lutidine) (lutidine = 2,6-lutidine) and manganese powder afforded the cross-coupled product in high yield. A mechanistic study indicated the intermediacy of the benzyl radicals that originate from the benzyl alcohols. | |||||||||
| 内容記述 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | Embargo Period 12 months | |||||||||
| 内容記述 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | This work was supported in part by a Mitsui Chemicals Award in Synthetic Organic Chemistry, Japan, a UBE Industries Foundation Award, and the Kanazawa University SAKIGAKE project. | |||||||||
| 権利 | ||||||||||
| 権利情報 | Copyright © 2018 American Chemical Society | |||||||||
| 著者版フラグ | ||||||||||
| 出版タイプ | AM | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||
| 関連URI | ||||||||||
| 識別子タイプ | URI | |||||||||
| 関連識別子 | https://pubs.acs.org/doi/10.1021/acs.orglett.8b03367 | |||||||||
| 関連名称 | https://pubs.acs.org/doi/10.1021/acs.orglett.8b03367 | |||||||||
