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Aggregation behavior of fluorooctanols in hydrocarbon solvents
https://doi.org/10.24517/00065561
https://doi.org/10.24517/00065561d9e19043-6865-4121-8f7c-938a1944a6f6
| 名前 / ファイル | ライセンス | アクション |
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SC-PR-ASAKAWA-T-107-11502.pdf (208.0 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||
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| 公開日 | 2022-03-11 | |||||||||
| タイトル | ||||||||||
| タイトル | Aggregation behavior of fluorooctanols in hydrocarbon solvents | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| ID登録 | ||||||||||
| ID登録 | 10.24517/00065561 | |||||||||
| ID登録タイプ | JaLC | |||||||||
| 著者 |
Ohta, Akio
× Ohta, Akio× Murakami, Ryo× Urata, Akiko× Asakawa, Tsuyoshi× Miyagishi, Shigeyoshi× Aratono, Makoto |
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| 著者別表示 |
太田, 明雄
× 太田, 明雄
× 淺川, 毅
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| 提供者所属 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | 金沢大学理工研究域物質化学系 | |||||||||
| 書誌情報 |
Journal of Physical Chemistry B 巻 107, 号 41, p. 11502-11509, 発行日 2003-10-16 |
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| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 1520-6106 | |||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 1520-5207 | |||||||||
| NCID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AA11114073 | |||||||||
| DOI | ||||||||||
| 関連タイプ | isIdenticalTo | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.1021/jp035134o | |||||||||
| 出版者 | ||||||||||
| 出版者 | American Chemical Society | |||||||||
| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | The association behaviors of three 1-octanols (1-octanol: C8OH; 1,1,2,2-tetrahydrotridecafluorooctanol TFC8OH; and 1,1-dihydropentadecafluorooctanol: DFC8OH) in two hydrocarbon solvents (n-hexane and benzene) were examined by vibration spectroscopy from 288.15 to 318.15 K. From the analysis of results with a mass action model, it was found that dimers and tetramers of 1-octanols coexisted with monomers in the n-hexane solution. These aggregates were formed by hydrogen bonding between the OH groups of 1-octanols. In the n-hexane solutions, an increase in the fluorination number of the 1-octanol molecule enhanced the intermolecular hydrogen bonding between the OH groups, but reduced the amounts of polymeric species. Conversely, in the benzene solution, the NIR experiment suggested that the OH groups of 1-octanols did not interact with other OH groups, but with the benzene molecules instead. It was found from 19F NMR chemical shift measurements that the fluorooctanols in the benzene solution aggregated by interaction between the fluorocarbon chains instead of by hydrogen bonding. | |||||||||
| 権利 | ||||||||||
| 権利情報 | Copyright © 2003 American Chemical Society | |||||||||
| 著者版フラグ | ||||||||||
| 出版タイプ | VoR | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||
| 関連URI | ||||||||||
| 識別子タイプ | URI | |||||||||
| 関連識別子 | http://pubs.acs.org/journal/jpcbfk | |||||||||
| 関連名称 | http://pubs.acs.org/journal/jpcbfk | |||||||||
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| 識別子タイプ | URI | |||||||||
| 関連識別子 | http://pubs.acs.org/ | |||||||||
| 関連名称 | http://pubs.acs.org/ | |||||||||
| 関連URI | ||||||||||
| 識別子タイプ | URI | |||||||||
| 関連識別子 | https://pubs.acs.org/doi/10.1021/jp035134o | |||||||||
| 関連名称 | https://pubs.acs.org/doi/10.1021/jp035134o | |||||||||
