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What determines the size of liquid capillary condensates below the bulk melting point?
https://doi.org/10.24517/00065564
https://doi.org/10.24517/0006556476aac5f9-b7ba-40f1-999a-b8ee50e0cf8e
| 名前 / ファイル | ライセンス | アクション |
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SC-PR-ASAKAWA-T-111-2141.pdf (146.7 kB)
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| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||||
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| 公開日 | 2022-03-11 | |||||||
| タイトル | ||||||||
| タイトル | What determines the size of liquid capillary condensates below the bulk melting point? | |||||||
| 言語 | ||||||||
| 言語 | eng | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | journal article | |||||||
| ID登録 | ||||||||
| ID登録 | 10.24517/00065564 | |||||||
| ID登録タイプ | JaLC | |||||||
| 著者 |
Barber, P.
× Barber, P.× Asakawa, Tsuyoshi× Christenson, H.K. |
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| 著者別表示 |
淺川, 毅
× 淺川, 毅
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| 提供者所属 | ||||||||
| 内容記述タイプ | Other | |||||||
| 内容記述 | 金沢大学理工研究域物質化学系 | |||||||
| 書誌情報 |
Journal of Physical Chemistry C 巻 111, 号 5, p. 2141-2148, 発行日 2007-01-12 |
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| ISSN | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 1932-7447 | |||||||
| ISSN | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 1932-7455 | |||||||
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| 収録物識別子タイプ | NCID | |||||||
| 収録物識別子 | AA1217589X | |||||||
| DOI | ||||||||
| 関連タイプ | isIdenticalTo | |||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | 10.1021/jp066556b | |||||||
| 出版者 | ||||||||
| 出版者 | American Chemical Society | |||||||
| 抄録 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | Capillary condensation from vapor has been studied at temperatures below the bulk melting point Tm of the condensing substance using a surface force apparatus. Both mica and mica modified by self-assembly of a fluorinated surfactant (perfluoro-1H,1H,2H,2H-decylpyridinium chloride) have been used as substrate surfaces. The condensing liquids, cyclooctane and menthol, nearly wet (contact angle <15°) mica but show a high (∼60°) contact angle on the fluorinated surface. As in previous studies with unmodified mica, we find that both cyclooctane and menthol condense as liquids below Tm, and that the size of the condensates at solid-vapor coexistence is limited and inversely proportional to the temperature depression below Tm, or Ar. A comparison of the size of the condensates between the fluorocarbon surfaces and the mica surfaces and the quantitative dependence of the size of the condensate on ΔT for cyclooctane lead us to conclude that the maximum condensate size is determined by the equilibrium between condensed, "supercooled" liquid and vapor, and is hence proportional to the surface tension of the liquid-vapor interface. From a consideration of the equilibrium between a liquid and a hypothetical solid condensate, it is concluded that a solid condensate does not usually form for kinetic reasons although two exceptions were found in earlier work. © 2007 American Chemical Society. | |||||||
| 権利 | ||||||||
| 権利情報 | Copyright © 2007 American Chemical Society | |||||||
| 著者版フラグ | ||||||||
| 出版タイプ | VoR | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| 関連URI | ||||||||
| 識別子タイプ | URI | |||||||
| 関連識別子 | http://pubs.acs.org/journal/jpccck/about.html | |||||||
| 関連名称 | http://pubs.acs.org/journal/jpccck/about.html | |||||||
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| 識別子タイプ | URI | |||||||
| 関連識別子 | http://pubs.acs.org/ | |||||||
| 関連名称 | http://pubs.acs.org/ | |||||||
| 関連URI | ||||||||
| 識別子タイプ | URI | |||||||
| 関連識別子 | https://pubs.acs.org/doi/10.1021/jp066556b | |||||||
| 関連名称 | https://pubs.acs.org/doi/10.1021/jp066556b | |||||||
