{"_buckets": {"deposit": "d5e9c194-62be-4d31-90ba-4522a2e41c4d"}, "_deposit": {"created_by": 18, "id": "61569", "owners": [18], "pid": {"revision_id": 0, "type": "depid", "value": "61569"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00061569", "sets": ["937"]}, "author_link": ["108316", "78456", "16518", "16409", "79754", "108315", "79300", "79299", "2433"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicPageStart": "113566", "bibliographicVolumeNumber": "856", "bibliographic_titles": [{"bibliographic_title": "Journal of Electroanalytical Chemistry"}]}]}, "item_4_creator_33": {"attribute_name": "著者別表示", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "山本, 翔"}], "nameIdentifiers": [{"nameIdentifier": "78456", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "西山, 嘉男"}], "nameIdentifiers": [{"nameIdentifier": "79299", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "40617487", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=40617487"}]}, {"creatorNames": [{"creatorName": "井村, 久則"}], "nameIdentifiers": [{"nameIdentifier": "2433", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60142923", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60142923"}]}, {"creatorNames": [{"creatorName": "永谷, 広久"}], "nameIdentifiers": [{"nameIdentifier": "79754", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "90346297", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=90346297"}, {"nameIdentifier": "90346297", "nameIdentifierScheme": "金沢大学研究者情報", "nameIdentifierURI": "http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=90346297"}, {"nameIdentifier": "90346297", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000090346297"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The transfer mechanism and adsorption state of water-soluble 8-quinolinolate complexes were studied at the water|1,2-dichloroethane interface by electrochemical and spectroelectrochemical techniques. The interfacial affinities of the metal complexes of 8-hydroxyquinoline-5-sulfonate (QS) were estimated as ,  \u003e . Potential modulated fluorescence spectroscopy revealed the potential-driven process of fluorescent QS complexes, where Al(III) and Zn(II) complexes were transferred across the interface accompanied by the adsorption at the aqueous side of the interface. The adsorption state and preferential molecular orientation of these complexes were analyzed in detail by polarization-modulation total internal reflection fluorescence (PM-TIRF) spectroscopy. The PM-TIRF results showed that the square-planar 1:2 complexes,  and , were oriented relatively in parallel to the interface and approximately identical to the aqueous species. The adsorption behavior of the Zn(II) complex of tridentate 8-hydroxyquinoline-2-carboxylate (QC) ligand was also investigated, and  exhibited a strong interfacial affinity with intermediate spectral features between the aqueous and organic species.", "subitem_description_type": "Abstract"}]}, "item_4_description_22": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "Embargo Period 12 months", "subitem_description_type": "Other"}, {"subitem_description": "This paper has a Supplementary material.", "subitem_description_type": "Other"}]}, "item_4_description_5": {"attribute_name": "提供者所属", "attribute_value_mlt": [{"subitem_description": "金沢大学理工研究域物質化学系", "subitem_description_type": "Other"}]}, "item_4_identifier_registration": {"attribute_name": "ID登録", "attribute_value_mlt": [{"subitem_identifier_reg_text": "10.24517/00067812", "subitem_identifier_reg_type": "JaLC"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier / International Society of Electrochemistry (ISE)"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1016/j.jelechem.2019.113566", "subitem_relation_type_select": "DOI"}}]}, "item_4_relation_28": {"attribute_name": "関連URI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "https://www.sciencedirect.com/journal/journal-of-electroanalytical-chemistry"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://www.sciencedirect.com/journal/journal-of-electroanalytical-chemistry", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "https://www.ise-online.org/"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://www.ise-online.org/", "subitem_relation_type_select": "URI"}}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright © 2019 Elsevier B. 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