{"_buckets": {"deposit": "7d59adb5-2788-4192-8518-75a0c5494d45"}, "_deposit": {"created_by": 18, "id": "61689", "owners": [18], "pid": {"revision_id": 0, "type": "depid", "value": "61689"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00061689", "sets": ["2846"]}, "author_link": ["107989"], "item_9_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1989-03-29", "bibliographicIssueDateType": "Issued"}, "bibliographicPageStart": "2p.", "bibliographicVolumeNumber": "1986 – 1987", "bibliographic_titles": [{"bibliographic_title": "昭和62(1987)年度 科学研究費補助金 一般研究(B) 研究成果報告書概要"}, {"bibliographic_title": "1987 Fiscal Year Final Research Report Summary", "bibliographic_titleLang": "en"}]}]}, "item_9_creator_33": {"attribute_name": "著者別表示", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Itoh, Michiya"}], "nameIdentifiers": [{"nameIdentifier": "107989", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30012610", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30012610"}]}]}, "item_9_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "1.フルオレンと9-エチフルオレン間でファンデルクール錯体の生成することを超音速ジェット中で見出し, その光励起によりエクサイプレックス蛍光をはじめて観測した. この錯体からエクサイプレックスの生成には, 励起エネルギー依存性が見られず, また, エクサイプレックス生成における錯体蛍光寿命が非常に短いことから, 錯体よりエクサイプレックスの生成は非常に速く起ることが明らかとなった.\n2.フルオレンとアルキルベンゼンやクロベンゼン類との間のファンデルワールス錯体の生成を超音速ジェット中で見した. そして錯体の蛍光励起スペクトルに〓し〓分子間振動によるスペクトルを観測した.\n3.1-シアノー4-メチルナフタレンおよび1-シアノー2-メチルナフタレンとトリエチルアミンとの間で, ファンデルクールス錯体の生成を見出した. とくに1-シアノー4-メチルナフタレンとトリエチルアミンでの錯体では, 2種類の錯体をはじめて見出し, 一方の錯体では励起状態から容易にエクサイプレックスを生成することを見出した. しかし他の錯体では, 最低のエネルギー状態からはエクサイプレッスを生成せず, わずかに振動エネルギーの高い状態からエクサイプレッスの生成することを明らかにした. そして錯体よりエクサイプレッスの生成における分子間振動の役割について検討した.", "subitem_description_type": "Abstract"}, {"subitem_description": "1. The exciplex formation dynamics of the 1-cyanonaphthalene/triethylamine van der Waals complex upon excitation has been examined under collision free condition. Mode-specificity has been found in the excitation of a combination band between intra- and intermolecular vibrational modes in the S_1 state of the vdW complex to promote the exciplex formation reaction.\nThe fluorescence decays of the S1 and exciplex states have been measured as a function of excess energy above the S1 origdn. The observed decay rate constants have been discussed using a simple kinetic model.\n2. Upon excitation of the van der Waals dimer and heterodimer of fluorene and 9-ethylfluorene generated in a supersonic expansion, the excimer and exciplex fluorescence spectra and decay times were obtained, The spectral maximum and decay time of the exciplex are almost intermediate between two excimers of fluorene and 9-ethylfluorene. The transformation of vdW heterodimer to the exciplex takes place from the excited state of the heterodimer corresponding to the locally excited state of 9-ethylfluorene.\n3. Two types of van der Waals complexes between 1-cyano-4-methylnaphthalene and triethylamine were obvserved in the supersonic free jet. Upon excitation of neraly origin bands of these complexes, the dispersed exciplex fluorescence was observed from one of the complexes, while no significnat exciplex fluorescence was detected from the other complex. However, the fluorescence excitation spectra demonstrate that the transformation to the exciplex proceeds in the excitation to the uper vibrational state of these complexes. The exciplex fromation from the vdW complex was also indicated by the determination of fluorescence decay times of these jet cooled species.", "subitem_description_type": "Abstract"}]}, "item_9_description_22": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "研究課題/領域番号:61470004, 研究期間(年度):1986 – 1987", "subitem_description_type": "Other"}, {"subitem_description": "出典：研究課題「ファンデァロールス錯体よりエクサイプレックス生成における動的過程の研究」課題番号61470004\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-61470004/614700041987kenkyu_seika_hokoku_gaiyo/）を加工して作成", "subitem_description_type": "Other"}]}, "item_9_description_5": {"attribute_name": "提供者所属", "attribute_value_mlt": [{"subitem_description": "金沢大学薬学部", "subitem_description_type": "Other"}]}, "item_9_identifier_registration": {"attribute_name": "ID登録", "attribute_value_mlt": [{"subitem_identifier_reg_text": "10.24517/00067932", "subitem_identifier_reg_type": "JaLC"}]}, "item_9_relation_28": 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"application/pdf", "size": 81200.0, "url": {"label": "PH-PR-ITOH-M-kaken 1989-2p.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/61689/files/PH-PR-ITOH-M-kaken 1989-2p.pdf"}, "version_id": "cabe24db-9663-4723-b124-2b737992585d"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "ファン・デル・ワールス錯体", "subitem_subject_scheme": "Other"}, {"subitem_subject": "エクサイプレックス", "subitem_subject_scheme": "Other"}, {"subitem_subject": "分子間振動", "subitem_subject_scheme": "Other"}, {"subitem_subject": "振動エネルギー依存性", "subitem_subject_scheme": "Other"}, {"subitem_subject": "シアノナフタレン", "subitem_subject_scheme": "Other"}, {"subitem_subject": "分子内振動エネルギーの再分配", "subitem_subject_scheme": "Other"}, {"subitem_subject": "van der Waals complex", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Supersonic jet", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Exciplex", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Excimer", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Fluorescence", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Transformation of van der Waals complex to Exciplex", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "ファンデァロールス錯体よりエクサイプレックス生成における動的過程の研究", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "ファンデァロールス錯体よりエクサイプレックス生成における動的過程の研究"}, {"subitem_title": "Intermolecular Dynamics and Exciplex Formation of van der Waals Complexes", "subitem_title_language": "en"}]}, 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