{"_buckets": {"deposit": "b560b81d-d3f0-4181-a354-d5dc1655c1de"}, "_deposit": {"created_by": 3, "id": "10250", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "10250"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00010250", "sets": ["4188"]}, "author_link": ["15140", "15339", "15335", "15338", "15337", "95392", "15334", "15336"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2001-07-15", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "4", "bibliographicPageEnd": "045211-7", "bibliographicPageStart": "045211-1", "bibliographicVolumeNumber": "64", "bibliographic_titles": [{"bibliographic_title": "Physical Review B"}]}]}, "item_4_creator_33": {"attribute_name": "著者別表示", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "遠藤, 一央"}], "nameIdentifiers": [{"nameIdentifier": "95392", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20293334", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20293334"}]}]}, "item_4_description_16": {"attribute_name": "その他の識別子", "attribute_value_mlt": [{"subitem_description": "AA11187113", "subitem_description_type": "Other"}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The results of x-ray fluorescence measurements of thiophenes @regioregular poly ~3-hexylthiophene ~P3HT! and a,v-dihexylquaterthiophene ~DHa4T!# and phtalocyanines @copper phtalocyanine ~CuPc! and copper hexadecafluorophtalocyanine (F16CuPc)# are presented. Experimental carbon, nitrogen, fluorine Ka and sulphur, copper L2,3 x-ray emission spectra are compared with ultraviolet photoemission spectroscopy spectra and deMon density-functional theory calculations of model molecules. We find that the carbon Ka emission is almost identical for P3HT and DHa4T. This indicates that the electronic structure of the p system is not affected by the presence of the side group. The ratio of emission intensities of the Cu L2 to Cu L3 intensities is found to be smaller by a factor of 2 for CuPc and F16CuPc than it is for pure metal. This demonstrates the strong covalency in phalocyanines.", "subitem_description_type": "Abstract"}]}, "item_4_description_5": {"attribute_name": "提供者所属", "attribute_value_mlt": [{"subitem_description": "金沢大学ナノマテリアル研究所 / 金沢大学理工研究域数物科学系 / 金沢大学大学院自然科学研究科物質情報解析", "subitem_description_type": "Other"}]}, "item_4_identifier_registration": {"attribute_name": "ID登録", "attribute_value_mlt": [{"subitem_identifier_reg_text": "10.24517/00010237", "subitem_identifier_reg_type": "JaLC"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The American Physical Society"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1103/physrevb.64.045211", "subitem_relation_type_select": "DOI"}}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2000 The American Physical Society"}]}, "item_4_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "10980121", "subitem_source_identifier_type": "ISSN"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kurmaev, E.Z."}], "nameIdentifiers": [{"nameIdentifier": "15334", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shamin, S.N."}], "nameIdentifiers": [{"nameIdentifier": "15335", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Galakhov, V.R."}], "nameIdentifiers": [{"nameIdentifier": "15336", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Moewes, A."}], "nameIdentifiers": [{"nameIdentifier": "15337", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Otsuka, T."}], "nameIdentifiers": [{"nameIdentifier": "15338", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Koizume, S."}], "nameIdentifiers": [{"nameIdentifier": "15339", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Endo, Kazunaka"}], "nameIdentifiers": [{"nameIdentifier": "15140", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20293334", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20293334"}, {"nameIdentifier": "20293334", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000020293334"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-03"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "SC-PR-ENDO-K-e045211.pdf", "filesize": [{"value": "123.4 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_11", "mimetype": "application/pdf", "size": 123400.0, "url": {"label": "SC-PR-ENDO-K-e045211.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/10250/files/SC-PR-ENDO-K-e045211.pdf"}, "version_id": "7361a16d-f18c-41d3-9c8d-1a4601e0f512"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Electronic structure of thiophenes and phthalocyanines", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Electronic structure of thiophenes and phthalocyanines"}]}, "item_type_id": "4", "owner": "3", "path": ["4188"], "permalink_uri": "https://doi.org/10.24517/00010237", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-03"}, "publish_date": "2017-10-03", "publish_status": "0", "recid": "10250", "relation": {}, "relation_version_is_last": true, "title": ["Electronic structure of thiophenes and phthalocyanines"], "weko_shared_id": 3}