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Calorimetric Investigation of N-Acyl Amino Acids
http://hdl.handle.net/2297/38265
http://hdl.handle.net/2297/382658a4ecf5c-bca4-46d8-ae31-a715ff67f529
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-ASAKAWA-T-1019.pdf (514.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-10-03 | |||||
| タイトル | ||||||
| タイトル | Calorimetric Investigation of N-Acyl Amino Acids | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Shigeyoshi, Miyagishi
× Shigeyoshi, Miyagishi× Matsumura, Seiichi× Murata, Kazuhiko× Asakawa, Tsuyoshi× Nishida, Morie |
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| 書誌情報 |
Bulletin of the Chemical Society of Japan 巻 58, 号 3, p. 1019-1022, 発行日 1985-01-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0009-2673 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00580132 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1246/bcsj.58.1019 | |||||
| 出版者 | ||||||
| 出版者 | The Chemical Society of Japan = 日本化学会 | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The melting characteristics of N-acyl amino acids were examined using a differential scanning calorimeter (DSC). The melting-point temperature of N-dodecanoyl L-amino acid increased with the size of its amino acid residue, while the order was opposite for the DL-amino acids. The racemic derivatives formed racemic compounds in their solid states. Each N-dodecanoyl L-amino acid had a larger enthalpy and entropy-of-fusion than its racemic isomer. Differences in the thermodynamic quantities between the optically active and racemic isomers were larger for N-dodecanoylvaline and -leucine compared with those of N-dodecanoylalanine. A mixture of these molecules were also studied. Each racemic isomer of N-dodecanoylalanine and -leucine partly formed a racemic pair in the liquid state. | |||||
| 権利 | ||||||
| 権利情報 | Copyright © The Chemical Society of Japan 日本化学会 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 関連URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://www.jstage.jst.go.jp/browse/bcsj | |||||
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| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.chemistry.or.jp/ | |||||
