| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2017-10-03 |
| タイトル |
|
|
タイトル |
(Z)-Selective enol triflation of α-alkoxyacetoaldehydes: Application to synthesis of (Z)-allylic alcohols via cross-coupling reaction and [1,2]-wittig rearrangement |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| ID登録 |
|
|
ID登録 |
10.24517/00010748 |
|
ID登録タイプ |
JaLC |
| 著者 |
Kurosawa, Fumiya
Nakano, Takeo
Soeta, Takahiro
Endo, Kohei
Ukaji, Yutaka
|
| 著者別表示 |
中野 , 武雄
添田, 貴宏
遠藤, 恆平
宇梶, 裕
|
| 書誌情報 |
Journal of Organic Chemistry
巻 80,
号 11,
p. 5696-5703,
発行日 2015-06-05
|
| ISSN |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0022-3263 |
| NCID |
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収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA00704100 |
| DOI |
|
|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
10.1021/acs.joc.5b00647 |
| 出版者 |
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出版者 |
American Chemical Society |
| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
The stereoselective transformation of α-alkoxyacetoaldehydes to the corresponding (Z)-vinyl triflates was achieved by treatment with phenyl triflimide and DBU. The stereochemistry was explained by the "syn-effect," which was attributed primarily to an σ → π∗ interaction. The β-alkoxy vinyl triflates obtained were applied to the stereoselective synthesis of structurally diverse (Z)-allylic alcohols via transition metal-catalyzed cross-coupling reaction and [1,2]-Wittig rearrangement. © 2015 American Chemical Society. |
| 著者版フラグ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
SC-PR-UKAJI-Y-5696.pdf (410.8 kB)
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