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Synthesis of a bowl-type dodecavanadate by the coupling reaction of alkoxohexavanadate and discovery of a chiral octadecavanadate
http://hdl.handle.net/2297/19143
http://hdl.handle.net/2297/19143b29bcbef-7a60-4342-b0fe-300fd1b7c4f6
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-HAYASHI-Y-1323.pdf (516.4 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-10-03 | |||||
| タイトル | ||||||
| タイトル | Synthesis of a bowl-type dodecavanadate by the coupling reaction of alkoxohexavanadate and discovery of a chiral octadecavanadate | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Domae, Kyosuke
× Domae, Kyosuke× Uchimura, Daisuke× Koyama, Yuuki× Inami, Shinnosuke× Hayashi, Yoshihito× Isobe, Kiyoshi× Kameda, Hiroyuki× Shimoda, Tatsuya |
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| 提供者所属 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 金沢大学理工研究域物質化学系 | |||||
| 書誌情報 |
Pure and Applied Chemistry 巻 81, 号 7, p. 1323-1330, 発行日 2009-01-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0033-4545 | |||||
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| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00797859 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1351/PAC-CON-08-08-25 | |||||
| 出版者 | ||||||
| 出版者 | International Union of Pure and Applied Chemistry | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A new route to an alkoxohexavanadate species leads to the isolation of a bowl-type dodecavanadate without a guest molecule in the cavity. The 1D tetravanadate, [V4O11]2-, is a good precursor for the alkoxohexavanadate, [V6O13(OCH3)6]2-, which is then utilized for the [V6 + V6] coupling reaction to form the dodecavanadate, [V12O42]4-, with a capped dichloromethane molecule at the cavity entrance. We also obtained structural information on a newly discovered octadecavanadate, [V18O46(NO3)]5-, in both the solid and solution states through extended X-ray absorption fine structure (EXAFS) studies. The existence of the chiral inorganic species in acetonitrile with double-stranded V8 chains was confirmed through EXAFS oscillations. © 2009 IUPAC. | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
