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Chromatographic Simulation of the Effect of a Polyvalent Counter Ion on Retention Behavior and Peak Intensity of Sulfate
http://hdl.handle.net/2297/44527
http://hdl.handle.net/2297/44527c478c0c4-b440-4458-844d-e04da3a26cc8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
PH-PR-HAYAKAWA-K-755.pdf (232.4 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-10-04 | |||||
| タイトル | ||||||
| タイトル | Chromatographic Simulation of the Effect of a Polyvalent Counter Ion on Retention Behavior and Peak Intensity of Sulfate | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Nishimura, Masayuki
× Nishimura, Masayuki× Hayashi, Morimasa× Yamamoto, Atsushi× Hayakawa, Kazuichi× Miyazaki, Motoichi |
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| 書誌情報 |
Analytical Sciences 巻 11, 号 5, p. 755-758, 発行日 1995-01-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0910-6340 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA10500785 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.2116/analsci.11.755 | |||||
| 出版者 | ||||||
| 出版者 | 日本分析化学会 = The Japan Society for Analytical Chemistry | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The effect of a mobile phase polyvalent counter ion on the retention behavior and peak intensity of sulfate in non- suppressed ion chromatography was quantitatively studied using a chromatogram simulation method. In this study, both indirect photometric detection (IPD) method and conductometric detection (CD) method were evaluated. With the IPD method, the retention of sulfate was observed to decrease in the presence of the polyvalent counter ion (Trien) without any change in peak intensity. With the CD method, however, peak intensity of sulfate decreased and, under some conditions, gave a negative peak in simulation as was also observed in actual experiments. The present work demonstrates the possibility of predicting the effect of a polyvalent counter ion on sulfate retention without resorting to physical experiments. | |||||
| 権利 | ||||||
| 権利情報 | Copyright © The Japan Society for Analytical Chemistry | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 関連URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://www.jstage.jst.go.jp/browse/analsci | |||||
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| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.jsac.jp/ | |||||
