WEKO3
インデックスリンク
アイテム
One‐Shot Radical Cross Coupling Between Benzyl Alcohols and Alkenyl Halides Using Ni/Ti/Mn System
https://doi.org/10.24517/00060329
https://doi.org/10.24517/00060329932ba033-1147-4f1d-a087-cd6cf3625ab0
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-SUGA-T-5622.pdf (4.7 MB)
|
.png)
|
| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2020-12-24 | |||||||||
| タイトル | ||||||||||
| タイトル | One‐Shot Radical Cross Coupling Between Benzyl Alcohols and Alkenyl Halides Using Ni/Ti/Mn System | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| ID登録 | ||||||||||
| ID登録 | 10.24517/00060329 | |||||||||
| ID登録タイプ | JaLC | |||||||||
| 著者 |
Suga, Takuya
× Suga, Takuya× Takahashi , Yuuki× Ukaji, Yutaka |
|||||||||
| 著者別表示 |
菅, 拓也
× 菅, 拓也
× 宇梶, 裕
|
|||||||||
| 提供者所属 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | 金沢大学理工学域物質科学系 | |||||||||
| 書誌情報 |
Advanced Synthesis & Catalysis (ASC) 巻 362, 号 24, p. 5622-5626, 発行日 2020-10-22 |
|||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 1615-4150 | |||||||||
| NCID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AA11553845 | |||||||||
| DOI | ||||||||||
| 関連タイプ | isIdenticalTo | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.1002/adsc.202000945 | |||||||||
| 出版者 | ||||||||||
| 出版者 | Wiley | |||||||||
| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | A “one‐shot” cross coupling between benzyl alcohols and alkenyl halides has been established. A combination of low‐valent Ti‐mediated C−OH homolysis and the prominent chemistry of Ni‐based radical catalysis afforded the desired cross‐coupled product with good efficiency. The reaction proceeded regardless of the electronic property of benzyl alcohols, and Ar−B bond remained intact throughout the reaction. Alkenyl bromides with various substitution patterns were applicable to this reaction. Attempts for utilizing sterically demanding tri‐substituted alkenes indicated that the steric hinderance mainly inhibited the radical‐trapping by Ni species. This reaction can be a simple and efficient strategy for synthesizing densely substituted allylbenzene derivatives. | |||||||||
| 権利 | ||||||||||
| 権利情報 | Copyright © 2020 Wiley‐VCH GmbH | |||||||||
| 著者版フラグ | ||||||||||
| 出版タイプ | VoR | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||
| 関連URI | ||||||||||
| 識別子タイプ | URI | |||||||||
| 関連識別子 | http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1615-4169/ | |||||||||
| 関連名称 | http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1615-4169/ | |||||||||
| 関連URI | ||||||||||
| 識別子タイプ | URI | |||||||||
| 関連識別子 | https://onlinelibrary.wiley.com/doi/10.1002/adsc.202000945 | |||||||||
| 関連名称 | https://onlinelibrary.wiley.com/doi/10.1002/adsc.202000945 | |||||||||
