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Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite
https://doi.org/10.24517/00065563
https://doi.org/10.24517/000655638dfa8a7e-f6ac-435e-a457-991d9fb9b0ef
| 名前 / ファイル | ライセンス | アクション |
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SC-PR-ASAKAWA-T-124-7760.pdf (7.3 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||
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| 公開日 | 2022-03-11 | |||||||||||||||
| タイトル | ||||||||||||||||
| タイトル | Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite | |||||||||||||||
| 言語 | ||||||||||||||||
| 言語 | eng | |||||||||||||||
| 資源タイプ | ||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||
| 資源タイプ | journal article | |||||||||||||||
| ID登録 | ||||||||||||||||
| ID登録 | 10.24517/00065563 | |||||||||||||||
| ID登録タイプ | JaLC | |||||||||||||||
| 著者 |
Asakawa, Hitoshi
× Asakawa, Hitoshi× Matsui, Sayaka× Trinh, Quang Than× Hirao, Hajime× Inokuma, Yasuhide× Ogoshi, Tomoki× Tanaka, Saki× Komatsu, Kayo× Ohta, Akio× Asakawa, Tsuyoshi× Fukuma, Takeshi |
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| 著者別表示 |
淺川, 雅
× 淺川, 雅
× 生越, 友樹
× 太田, 明雄
× 淺川, 毅
× 福間, 剛士
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| 提供者所属 | ||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||
| 内容記述 | 金沢大学ナノ生命科学研究所 / 金沢大学理工研究域物質化学系 | |||||||||||||||
| 書誌情報 |
Journal of Physical Chemistry C 巻 124, 号 14, p. 7760-7767, 発行日 2020-04-09 |
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| ISSN | ||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||
| 収録物識別子 | 1932-7447 | |||||||||||||||
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| 収録物識別子タイプ | ISSN | |||||||||||||||
| 収録物識別子 | 1932-7455 | |||||||||||||||
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| 収録物識別子タイプ | NCID | |||||||||||||||
| 収録物識別子 | AA1217589X | |||||||||||||||
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| 関連タイプ | isIdenticalTo | |||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||
| 関連識別子 | 10.1021/acs.jpcc.9b11246 | |||||||||||||||
| 出版者 | ||||||||||||||||
| 出版者 | American Chemical Society | |||||||||||||||
| 抄録 | ||||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||||
| 内容記述 | The self-assembly of organic molecules at the surface of highly oriented pyrolytic graphite (HOPG) is a promising process for constructing molecular-scale architectures. However, selectable organic molecules are generally restricted to two-dimensional molecules with planar Ï-conjugated structures and alkyl chains. We herein present the formation of self-assembled monolayers of tetrakis(4-ethynylphenyl)methane (TEPM) having a three-dimensional (3D) tetrapod geometry on HOPG, which was achieved by utilizing a simple spin-coating method. The arrangements of TEPM molecules in the monolayers were investigated using frequency-modulation atomic force microscopy (FM-AFM). The resulting subnanometer-resolution FM-AFM images revealed that the TEPM molecules formed linear rows with a periodicity of 0.85 nm oriented in a parallel configuration but with two alternating intervals of 0.7 and 1.0 nm. Moreover, the TEPM monolayers were classified into two chiral types with a relationship of mutual mirror-image symmetry, according to the observed molecular arrangements. Our results demonstrate the capability of TEPM molecules to act as 3D building blocks for the design of molecular-scale architectures at interfaces. Copyright © 2020 American Chemical Society. | |||||||||||||||
| 権利 | ||||||||||||||||
| 権利情報 | Copyright © 2020 American Chemical Society | |||||||||||||||
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| 出版タイプ | VoR | |||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||
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| 識別子タイプ | URI | |||||||||||||||
| 関連識別子 | http://pubs.acs.org/journal/jpccck/about.html | |||||||||||||||
| 関連名称 | http://pubs.acs.org/journal/jpccck/about.html | |||||||||||||||
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| 識別子タイプ | URI | |||||||||||||||
| 関連識別子 | http://pubs.acs.org/ | |||||||||||||||
| 関連名称 | http://pubs.acs.org/ | |||||||||||||||
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| 識別子タイプ | URI | |||||||||||||||
| 関連識別子 | https://pubs.acs.org/doi/10.1021/acs.jpcc.9b11246 | |||||||||||||||
| 関連名称 | https://pubs.acs.org/doi/10.1021/acs.jpcc.9b11246 | |||||||||||||||
