| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2017-10-02 |
| タイトル |
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タイトル |
Derivatographic Studies on Transition Metal Complexes. XX. Thermal Electron Transfer Reactions of Cobalt(III) Complexes Containing Phenylbiguanide in the Solid Phase |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
Ihara, Yoshinori
Uehara, Akira
Tsuchiya, Ryokichi
Kyuno, Eishin
|
| 著者別表示 |
井原, 良訓
土屋, 亮吉
上原, 章
久野, 栄進
|
| 書誌情報 |
Bulletin of the Chemical Society of Japan
巻 51,
号 9,
p. 2578-2582,
発行日 1978-01-01
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| ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
1348-0634 |
| NCID |
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収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA12026255 |
| DOI |
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関連タイプ |
isIdenticalTo |
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識別子タイプ |
DOI |
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関連識別子 |
10.1246/bcsj.51.2578 |
| 出版者 |
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出版者 |
日本化学会＝The Chemical Society of Japan |
| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
The following six cobalt(III) complexes containing phenylbiguanide were prepared and the thermal reactions were followed both isothermally and non-isothermally (derivatographically) in the solid phase: trans-[Co(A)2(phbgH)2]X3·n2O, where A denotes volatile ligands such as NH3, CH3NH2 or C5H5N; phbgH denotes 1-phenylbiguanide, X chloride or bromide ion; and n is 2 or 3. From the electronic, IR and far-IR spectra and magnetic susceptibilities of these complexes before and after heating, the products obtained by evolving volatile ligands were found to be uniform bivalent cobalt complexes without rupture of the bonds of phbgH to cobalt in spite of the reduction of central cobalt(III) ion, except for the complexes containing ammonia. The reaction seems to be caused by the electron transfer from the coordinated phbgH to cobalt, not from the outer-sphere anions. |
| 権利 |
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権利情報 |
Copyright © 日本化学会 The Chemical Society of Japan |
| 著者版フラグ |
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出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 関連URI |
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識別子タイプ |
URI |
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|
関連識別子 |
http://www.chemistry.or.jp/journal/index.html |
| 関連URI |
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識別子タイプ |
URI |
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|
関連識別子 |
https://www.jstage.jst.go.jp/article/bcsj1926/51/9/51_9_2578/_article |
LE-PR-IHARA-Y-2578-2582.pdf (1.4 MB)
