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Thermal Square Planar-to-Octahedral Transformation of Nickel(II) Complexes Containing 2-Aminobenzimidazole in the Solid Phase
http://hdl.handle.net/2297/37505
http://hdl.handle.net/2297/37505ccc9f6bb-b80c-45cc-8974-5b8c7d10bf40
名前 / ファイル | ライセンス | アクション |
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LE-PR-IHARA-Y-1614-1617.pdf (289.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-02 | |||||
タイトル | ||||||
タイトル | Thermal Square Planar-to-Octahedral Transformation of Nickel(II) Complexes Containing 2-Aminobenzimidazole in the Solid Phase | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ihara, Yoshinori
× Ihara, Yoshinori× Tsuchiya, Ryokichi |
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著者別表示 |
土屋, 亮吉
× 土屋, 亮吉× 井原, 良訓 |
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書誌情報 |
Bulletin of the Chemical Society of Japan 巻 53, 号 6, p. 1614-1617, 発行日 1980-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2673 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12026255 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/bcsj.53.1614 | |||||
出版者 | ||||||
出版者 | 日本化学会=The Chemical Society of Japan | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Thermal reactions of the complexes, [Ni(abi)4]X2·nH2O (abi, 2-aminobenzimidazole; X, Cl, Br, I, NO3, ClO4, or 1/2SO4; n, 3 for chloride and bromide, 1 for nitrate, and 0 for others) were investigated. Distinct color changes from orange to green were observed in the three complexes of chloride, bromide, and nitrate upon heating. It was found from the changes in absorption and far-IR spectra and magnetic susceptibilities under the thermal reactions that the complexes undergo transformation from square planar to tetragonally distorted octahedral structures, involving an increase in the coordination number from four to six. No such transformation could be found in the corresponding iodide, perchlorate, and sulfate. The effect of the introduced amino group on the structural conversion reactions of the abi complexes is discussed as compared with the corresponding benzimidazole complexes, [Ni(bimd)4]X2, which underwent transformation from square planar to octahedral structure upon heating when X is I or NO3. | |||||
権利 | ||||||
権利情報 | Copyright © 日本化学会 The Chemical Society of Japan|許可を得て登録 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.chemistry.or.jp/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/article/bcsj1926/53/6/53_6_1614/_article |