WEKO3
インデックスリンク
アイテム
{"_buckets": {"deposit": "75d4103c-e32d-47df-aa23-d035b2cea1a5"}, "_deposit": {"created_by": 3, "id": "828", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "828"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00000828", "sets": ["16"]}, "author_link": ["3936", "3934", "49959", "7928", "3932", "3939", "551", "3933"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1982-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "4", "bibliographicPageEnd": "1032", "bibliographicPageStart": "1028", "bibliographicVolumeNumber": "55", "bibliographic_titles": [{"bibliographic_title": "Bulletin of the Chemical Society of Japan"}]}]}, "item_4_creator_33": {"attribute_name": "著者別表示", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "井原, 良訓"}], "nameIdentifiers": [{"nameIdentifier": "551", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "70115210", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=70115210"}, {"nameIdentifier": "70115210", "nameIdentifierScheme": "金沢大学研究者情報", "nameIdentifierURI": "http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=70115210"}, {"nameIdentifier": "70115210", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000070115210"}]}, {"creatorNames": [{"creatorName": "上原, 章"}], "nameIdentifiers": [{"nameIdentifier": "49959", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30019484", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30019484"}]}, {"creatorNames": [{"creatorName": "土屋, 亮吉"}], "nameIdentifiers": [{"nameIdentifier": "7928", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "久野, 栄進"}], "nameIdentifiers": [{"nameIdentifier": "3934", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20019459", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20019459"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Thermal reactions of the [Ni(H2O)2(AA)2]X2·nH2O complexes in a solid phase were investigated, where AA is N,N′-diethylethylenediamine (NN′-deen), N,N-dimethylethylenediamine (NN-dmen), or N,N′-dimethylethylenediamine (NN′-dmen), and where X− is Cl−, Br−, I−, NO3− or ClO4−. By means of thermal analyses and spectral and magnetic measurements in a series of these complexes before and after heating, the following results were obtained. In the case of the NN′-deen complexes, only the perchlorate deaquates to change from octahedral to square-planar, but the other salts, such as the chloride, bromide, iodide, and nitrate, undergo deaquation-anation keeping their octahedral configuration. The deaquation-anation was also observed in the chloride, bromide, and nitrate of the NN-dmen complexes, but the iodide deaquated, and so was transformed from octahedral to square-planar. In the NN′-dmen complexes, only deaquation-anation was detected, irrespective of the anions (Cl−, Br−, I−, and NO3−). The effects of N-substituents in the diamines and the anions on the above transformation were discussed.", "subitem_description_type": "Abstract"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "日本化学会=The Chemical Society of Japan"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1246/bcsj.55.1028", "subitem_relation_type_select": "DOI"}}]}, "item_4_relation_28": {"attribute_name": "関連URI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.chemistry.or.jp/", "subitem_relation_type_select": "URI"}}, {"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://www.jstage.jst.go.jp/article/bcsj1926/55/4/55_4_1028/_article", "subitem_relation_type_select": "URI"}}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright © 日本化学会 The Chemical Society of Japan|許可を得て登録"}]}, "item_4_source_id_11": {"attribute_name": "NCID", "attribute_value_mlt": [{"subitem_source_identifier": "AA12026255", "subitem_source_identifier_type": "NCID"}]}, "item_4_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0009-2673", "subitem_source_identifier_type": "ISSN"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ihara, Yoshinori"}], "nameIdentifiers": [{"nameIdentifier": "551", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "70115210", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=70115210"}, {"nameIdentifier": "70115210", "nameIdentifierScheme": "金沢大学研究者情報", "nameIdentifierURI": "http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=70115210"}, {"nameIdentifier": "70115210", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000070115210"}]}, {"creatorNames": [{"creatorName": "Izumi, Eiichi"}], "nameIdentifiers": [{"nameIdentifier": "3936", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uehara, Akira"}], "nameIdentifiers": [{"nameIdentifier": "3932", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30019484", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30019484"}]}, {"creatorNames": [{"creatorName": "Tsuchiya, Ryokichi"}], "nameIdentifiers": [{"nameIdentifier": "3933", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakagawa, Shigeo"}], "nameIdentifiers": [{"nameIdentifier": "3939", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kyuno, Eishin"}], "nameIdentifiers": [{"nameIdentifier": "3934", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20019459", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20019459"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-02"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "LE-PR-IHARA-Y-1028-1032.pdf", "filesize": [{"value": "381.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 381600.0, "url": {"label": "LE-PR-IHARA-Y-1028-1032.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/828/files/LE-PR-IHARA-Y-1028-1032.pdf"}, "version_id": "8e295900-fff3-4f0d-b17b-4abab1512b5e"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase"}]}, "item_type_id": "4", "owner": "3", "path": ["16"], "permalink_uri": "http://hdl.handle.net/2297/37507", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-02"}, "publish_date": "2017-10-02", "publish_status": "0", "recid": "828", "relation": {}, "relation_version_is_last": true, "title": ["Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase"], "weko_shared_id": 3}
Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase
http://hdl.handle.net/2297/37507
http://hdl.handle.net/2297/3750766e9d796-2f0e-48b5-9ccc-269e9fcba80c
名前 / ファイル | ライセンス | アクション |
---|---|---|
LE-PR-IHARA-Y-1028-1032.pdf (381.6 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2017-10-02 | |||||
タイトル | ||||||
タイトル | Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ihara, Yoshinori
× Ihara, Yoshinori× Izumi, Eiichi× Uehara, Akira× Tsuchiya, Ryokichi× Nakagawa, Shigeo× Kyuno, Eishin |
|||||
著者別表示 |
井原, 良訓
× 井原, 良訓× 上原, 章× 土屋, 亮吉× 久野, 栄進 |
|||||
書誌情報 |
Bulletin of the Chemical Society of Japan 巻 55, 号 4, p. 1028-1032, 発行日 1982-01-01 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2673 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12026255 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/bcsj.55.1028 | |||||
出版者 | ||||||
出版者 | 日本化学会=The Chemical Society of Japan | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Thermal reactions of the [Ni(H2O)2(AA)2]X2·nH2O complexes in a solid phase were investigated, where AA is N,N′-diethylethylenediamine (NN′-deen), N,N-dimethylethylenediamine (NN-dmen), or N,N′-dimethylethylenediamine (NN′-dmen), and where X− is Cl−, Br−, I−, NO3− or ClO4−. By means of thermal analyses and spectral and magnetic measurements in a series of these complexes before and after heating, the following results were obtained. In the case of the NN′-deen complexes, only the perchlorate deaquates to change from octahedral to square-planar, but the other salts, such as the chloride, bromide, iodide, and nitrate, undergo deaquation-anation keeping their octahedral configuration. The deaquation-anation was also observed in the chloride, bromide, and nitrate of the NN-dmen complexes, but the iodide deaquated, and so was transformed from octahedral to square-planar. In the NN′-dmen complexes, only deaquation-anation was detected, irrespective of the anions (Cl−, Br−, I−, and NO3−). The effects of N-substituents in the diamines and the anions on the above transformation were discussed. | |||||
権利 | ||||||
権利情報 | Copyright © 日本化学会 The Chemical Society of Japan|許可を得て登録 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.chemistry.or.jp/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/article/bcsj1926/55/4/55_4_1028/_article |