| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2017-10-02 |
| タイトル |
|
|
タイトル |
Thermal Reactions of Octahedral Nickel(II) Complexes Containing N,N- and N,N′-Dialkylethylenediamines in a Solid Phase |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Ihara, Yoshinori
Izumi, Eiichi
Uehara, Akira
Tsuchiya, Ryokichi
Nakagawa, Shigeo
Kyuno, Eishin
|
| 著者別表示 |
井原, 良訓
上原, 章
土屋, 亮吉
久野, 栄進
|
| 書誌情報 |
Bulletin of the Chemical Society of Japan
巻 55,
号 4,
p. 1028-1032,
発行日 1982-01-01
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0009-2673 |
| NCID |
|
|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA12026255 |
| DOI |
|
|
関連タイプ |
isIdenticalTo |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1246/bcsj.55.1028 |
| 出版者 |
|
|
出版者 |
日本化学会＝The Chemical Society of Japan |
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Thermal reactions of the [Ni(H2O)2(AA)2]X2·nH2O complexes in a solid phase were investigated, where AA is N,N′-diethylethylenediamine (NN′-deen), N,N-dimethylethylenediamine (NN-dmen), or N,N′-dimethylethylenediamine (NN′-dmen), and where X− is Cl−, Br−, I−, NO3− or ClO4−. By means of thermal analyses and spectral and magnetic measurements in a series of these complexes before and after heating, the following results were obtained. In the case of the NN′-deen complexes, only the perchlorate deaquates to change from octahedral to square-planar, but the other salts, such as the chloride, bromide, iodide, and nitrate, undergo deaquation-anation keeping their octahedral configuration. The deaquation-anation was also observed in the chloride, bromide, and nitrate of the NN-dmen complexes, but the iodide deaquated, and so was transformed from octahedral to square-planar. In the NN′-dmen complexes, only deaquation-anation was detected, irrespective of the anions (Cl−, Br−, I−, and NO3−). The effects of N-substituents in the diamines and the anions on the above transformation were discussed. |
| 権利 |
|
|
権利情報 |
Copyright © 日本化学会 The Chemical Society of Japan｜許可を得て登録 |
| 著者版フラグ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 関連URI |
|
|
|
識別子タイプ |
URI |
|
|
関連識別子 |
http://www.chemistry.or.jp/ |
| 関連URI |
|
|
|
識別子タイプ |
URI |
|
|
関連識別子 |
https://www.jstage.jst.go.jp/article/bcsj1926/55/4/55_4_1028/_article |
LE-PR-IHARA-Y-1028-1032.pdf (381.6 kB)
