WEKO3
アイテム
X-Ray Crystal Structures of Octahedral Diaquabis(N,N-dialkyl-ethylenediamine)nickel(II) Complexes Possessing Elongated Nickel(II)–Nitrogen Bonds along Axial Direction
http://hdl.handle.net/2297/37512
http://hdl.handle.net/2297/3751286938967-6ccf-476d-9b75-cc34c54589f9
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
LE-PR-IHARA-Y-2349-2352.pdf (304.9 kB)
|
|
| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2017-10-02 | |||||||||||
| タイトル | ||||||||||||
| タイトル | X-Ray Crystal Structures of Octahedral Diaquabis(N,N-dialkyl-ethylenediamine)nickel(II) Complexes Possessing Elongated Nickel(II)–Nitrogen Bonds along Axial Direction | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| 著者 |
Ihara, Yoshinori
× Ihara, Yoshinori× Satake, Yasuhiro× Fujimoto, Yumi× Senda, Hitoshi× Suzuki, Masatatsu× Uehara, Akira |
|||||||||||
| 著者別表示 |
井原, 良訓
× 井原, 良訓
× 鈴木, 正樹
× 上原, 章
|
|||||||||||
| 書誌情報 |
Bulletin of the Chemical Society of Japan 巻 64, 号 8, p. 2349-2352, 発行日 1991-01-01 |
|||||||||||
| ISSN | ||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||
| 収録物識別子 | 0009-2673 | |||||||||||
| NCID | ||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||
| 収録物識別子 | AA12026255 | |||||||||||
| DOI | ||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1246/bcsj.64.2349 | |||||||||||
| 出版者 | ||||||||||||
| 出版者 | 日本化学会＝The Chemical Society of Japan | |||||||||||
| 抄録 | ||||||||||||
| 内容記述タイプ | Abstract | |||||||||||
| 内容記述 | The structures of two diaquabis(N,N-dialkylethylenediamine)nickel(II) chlorides ([Ni(H2O)2(diamine)2]Cl2·nH2O) were determined by X-ray crystallographic studies, where diamine is N,N-dimethylethylenediamine(NN-dmen) or N,N-diethylethylenediamine (NN-deen). Both complexes are trans and crystallize in the monoclinic space group P21⁄n. The unit cell parameters of the NN-dmen complex, NiCl2C8N4O2H32, are a=7.531(1), b=13.092(1), c=9.591 Å, β=107.76(1)°, and Z=2, and those of the NN-deen complex, NiCl2C12N4O2H36, are a=9.154(1), b=8.692(1), c=12.395(2) Å, β=104.46(1)°, and Z=2. In trans-[Ni(H2O)2(NN-dmen)2]Cl2·2H2O and trans-[Ni(H2O)2(NN-deen)2]Cl2, the Ni–NMe2 and Ni–NEt2 bond distances (2.183 and 2.271 Å) are much longer than the Ni–NH2 distances (2.078 and 2.064 Å), forming tetragonally distorted octahedrons with four close in-plane neighbors(N2O2) and two remote axial ones(N2). It is apparent that this distortion originates from the steric requirement of N-substituted groups. Such a distortion significantly affects the electronic spectra of these complexes. | |||||||||||
| 権利 | ||||||||||||
| 権利情報 | Copyright © 日本化学会 The Chemical Society of Japan｜許可を得て登録 | |||||||||||
| 著者版フラグ | ||||||||||||
| 出版タイプ | VoR | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||
| 関連URI | ||||||||||||
| 識別子タイプ | URI | |||||||||||
| 関連識別子 | http://www.chemistry.or.jp/ | |||||||||||
| 関連URI | ||||||||||||
| 識別子タイプ | URI | |||||||||||
| 関連識別子 | https://www.jstage.jst.go.jp/article/bcsj1926/64/8/64_8_2349/_article | |||||||||||
