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One-pot stereoselective synthesis of 2-acylaziridines and 2-acylpyrrolidines from N-(propargylic)hydroxylamines
https://doi.org/10.24517/00010573
https://doi.org/10.24517/000105731308db54-c08c-4fba-9606-26aa73f38a0c
| 名前 / ファイル | ライセンス | アクション |
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SC-PR-UKAJI-Y-824.pdf (643.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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| 公開日 | 2017-10-03 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | One-pot stereoselective synthesis of 2-acylaziridines and 2-acylpyrrolidines from N-(propargylic)hydroxylamines | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| ID登録 | ||||||||||||||
| ID登録 | 10.24517/00010573 | |||||||||||||
| ID登録タイプ | JaLC | |||||||||||||
| 著者 |
Miyamoto, Yoshiaki
× Miyamoto, Yoshiaki× Wada, Norihiro× Soeta, Takahiro× Fujinami, Shuhei× Inomata, Katsuhiko× Ukaji, Yutaka |
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| 著者別表示 |
添田, 貴宏
× 添田, 貴宏
× 藤波, 修平
× 猪股, 勝彦
× 宇梶, 裕
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| 書誌情報 |
Chemistry - An Asian Journal 巻 8, 号 4, p. 824-831, 発行日 2013-04-01 |
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| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 1861-4728 | |||||||||||||
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| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AA12151701 | |||||||||||||
| DOI | ||||||||||||||
| 関連タイプ | isVersionOf | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | 10.1002/asia.201201180 | |||||||||||||
| 出版者 | ||||||||||||||
| 出版者 | Wiley-VCH Verlag Berlin | |||||||||||||
| 抄録 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | The stereoselective direct transformation of N-(propargylic)hydroxylamines into cis-2-acylaziridines was achieved by the combined use of AgBF4 and CuCl. Copper salts were found to promote the transformation of the intermediary 4-isoxazolines into 2-acylaziridines and both 3-aryl- and 3-alkyl-substituted 2-acylaziridines could be prepared by using this method. Furthermore, subsequent 1,3-dipolar cycloaddition of azomethine ylides that were generated in situ from the intermediary 2-acylaziridines with maleimides was achieved in a stereoselective one-pot procedure to afford the corresponding 2-acylpyrrolidines, which consisted of an octahydropyrrolo[3,4-c]pyrrole skeleton. Love the way ylide: The transformation of N-(propargylic) hydroxylamines into cis-2-acylaziridines and subsequent 1,3-dipolar cycloaddition of the in situ generated azomethine ylides with maleimides stereoselectively afforded 2-acylpyrrolidines. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | |||||||||||||
| 著者版フラグ | ||||||||||||||
| 出版タイプ | AM | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||
