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Total syntheses of sterically locked phycocyanobilin derivatives bearing a 15Z-anti or a 15E-anti CD-ring component
https://doi.org/10.24517/00010661
https://doi.org/10.24517/00010661d76c35dc-3aeb-42d1-96ff-71d6bc1dbdb3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-INOMATA-K-1309.pdf (443.3 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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| 公開日 | 2017-10-03 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Total syntheses of sterically locked phycocyanobilin derivatives bearing a 15Z-anti or a 15E-anti CD-ring component | |||||||||||||
| 言語 | en | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| ID登録 | ||||||||||||||
| ID登録 | 10.24517/00010661 | |||||||||||||
| ID登録タイプ | JaLC | |||||||||||||
| 著者 |
Nishiyama, Kaori
× Nishiyama, Kaori× Kamiya, Ayumi× Hammam, Mostafa A. S.× Kinoshita, Hideki× Fujinami, Shuhei× Ukaji, Yutaka× Inomata, Katsuhiko |
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| 著者別表示 |
木下, 英樹
× 木下, 英樹
× 藤波, 修平
× 宇梶, 裕
× 猪股, 勝彦
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| 書誌情報 |
Bulletin of the Chemical Society of Japan 巻 83, 号 11, p. 1309-1322, 発行日 2010-01-01 |
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| ISSN | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 0009-2673 | |||||||||||||
| NCID | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AA00580132 | |||||||||||||
| 出版者 | ||||||||||||||
| 出版者 | The Chemical Society of Japan = 日本化学会 | |||||||||||||
| 抄録 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | Total syntheses of sterically locked phycocyanobilin derivatives with a 15Z-anti or a 15E-anti CD-ring component were performed toward elucidation of the stereochemistry and function of the chromophore in phytochromes. In the course of the construction of a sterically locked 15E-anti CD-ring component employing 5-tosylpyrrolin-2-one derivatives as the D-ring, the Ts group was found to be rearranged under acidic conditions to give a mixture of regioisomers, both of which could be transformed into the same CD-ring precursor via detosylation with a base followed by Wittig-like coupling reaction. In addition, a sterically locked 15E-anti biliverdin derivative was also synthesized. Total syntheses of sterically locked phycocyanobilin derivatives bearing a 15Z-anti or a 15E-anti CD-ring component were performed towards elucidation of the stereochemistry and function of the chromophore in phytochromes. | |||||||||||||
| 権利 | ||||||||||||||
| 権利情報 | Copyright © The Chemical Society of Japan 日本化学会 | |||||||||||||
| 著者版フラグ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
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| 関連タイプ | isVersionOf | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | https://doi.org/10.1246/bcsj.20100168 | |||||||||||||
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| 関連タイプ | isIdenticalTo | |||||||||||||
| 識別子タイプ | URI | |||||||||||||
| 関連識別子 | https://www.jstage.jst.go.jp/browse/bcsj | |||||||||||||
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| 関連タイプ | isIdenticalTo | |||||||||||||
| 識別子タイプ | URI | |||||||||||||
| 関連識別子 | http://www.chemistry.or.jp/ | |||||||||||||
